In situ reactive blending to prepare polystyrene-clay and polypropylene-clay nanocomposites

Authors

Dongyan Wang, Marquette UniversityFollow
Charles A. Wilkie, Marquette UniversityFollow

Document Type

Article

Publication Date

2003

Source Publication

Polymer Degradation and Stability

Source ISSN

0141-3910

Abstract

Nanocomposites of polystyrene and polypropylene with organically-modified clay may be prepared by melt blending in a Brabender mixer the clay and the polymer. The presence of maleic anhydride increases the likelihood of nanocomposite formation for polystyrene but is less important for polypropylene. The materials that result are immiscible materials, in that the clay is not uniformly distributed throughout the polymer matrix, but there is polymer inserted between the clay layers. The results from cone calorimetry suggest that nanocomposite formation has occurred, since there is a significant reduction in the peak heat release rate.

Comments

Accepted version. Polymer Degradation and Stability, Vol. 80, No. 1 (2003): 171-182. DOI. © 2003 Elsevier Science Ltd. Used with permission.

Recommended Citation

Wang, Dongyan and Wilkie, Charles A., "In situ reactive blending to prepare polystyrene-clay and polypropylene-clay nanocomposites" (2003). Chemistry Faculty Research and Publications. 145.
https://epublications.marquette.edu/chem_fac/145