Document Type

Article

Language

eng

Publication Date

1996

Publisher

International Union of Crystallography

Source Publication

Acta Crystallographica Section C

Source ISSN

0108-2701

Abstract

The structure of the title TeIV complex, C13H19BrN2OS4Te.045(CH2Cl2), is pentagonal bipyramidal with four S atoms [Te-S 2.623 (1)-2.717 (1) Å] and the Br atom [Te-Br 2.890 (1) Å] in equatorial positions. The p-methoxyphenyl group is axial [Te-C 2.145 (3) Å] and the second axial position seems to be occupied by a dithiocarbamate group of a neighbouring molecule acting as a -ligand [TeC 3.751 (3) Å, C-TeC 170.2 (1)°], so that molecules are joined into centrosymmetric associations by this secondary coordination.

Comments

Published version. Acta Crystallographica Section C, Vol. 52 (1996): 429-432. DOI. © International Union of Crystallography 1996. Used with permission.

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