The Chemistry Faculty Research and Publications Series is comprised of books and articles published by Marquette University's chemistry faculty.

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Submissions from 2010

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Infrared Spectroelectrochemical Reduction of Iron Porphyrin Complexes, Zhongcheng Wei and Michael Ryan

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Intermolecular Dehydrative Coupling Reaction of Arylketones with Cyclic Alkenes Catalyzed by a Well-Defined Cationic Ruthenium-Hydride Complex: A Novel Ketone Olefination Method via Vinyl C–H Bond Activation, Chae S. Yi and Do W. Lee

Submissions from 2009

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Material properties of nanoclay PVC composites, Walid Awad, Gunter Beyer, Daphne Benderly, Wouter L. Ijdo, Ponusa Songtipya, Maria del Mar Jimenez-Gasco, Evangelos Manias, and Charles Wilkie

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Development of Polyurea Nanocomposites with Improved Fire Retardancy, Walid Awad, Calistor Nyambo, Seogjun Kim, Robert J. Dinan, Jeff W. Fisher, and Charles Wilkie

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Linking Conformation Change to Hemoglobin Activation Via Chain-Selective Time-resolved Resonance Raman Spectroscopy on Protoheme/Mesoheme Hybrids, Gurusamy Balakrishnan, Mohammed Ibrahim, Piotr J. Mak, Jessica Hata, James R. Kincaid, and Thomas G. Spiro

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Subunit-Selective Interrogation of CO Recombination in Carbonmonoxy Hemoglobin by Isotope-Edited Time-Resolved Resonance Raman Spectroscopy, Gurusamy Balakrishnan, Xiaojie Zhao, Edyta Podstawska, Leonard M. Proniewicz, James R. Kincaid, and Thomas G. Spiro

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Recent Applications of Acyclic (Diene)iron Complexes and (Dienyl)iron Cations in Organic Synthesis, William Donaldson and Subhabrata Chaudhury

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Discriminating Pulmonary Hypertension Caused by Monocrotaline Toxicity from Chronic Hypoxia by Near-Infrared Spectroscopy and Multivariate Methods of Analysis, Simon Duri, Robert Molthen, and Chieu D. Tran

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Inhibitors of Bacterial N-succinyl-L,L-diaminopimelic Acid Desuccinylase (DapE) and Demonstration of in vitro Antimicrobial Activity, Danuta Gillner, Nicola Armoush, Richard C. Holz, and Daniel P. Becker

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The dapE-encoded N-succinyl-l,l-diaminopimelic Acid Desuccinylase from Haemophilus influenzae Contains Two Active-site Histidine Residues, Danuta Gillner, David L. Bienvenue, Boguslaw P. Nocek, Andzrej Joachimiak, Vincentos Zachary, Brian Bennett, and Richard C. Holz

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Synthetic studies directed toward guianolides: an organoiron route to the 5,7,5 tricyclic ring system, Jayapal Reddy Gone, Nathaniel J Wallock, Sergey Lindeman, and William Donaldson

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Effects of Hydroxy Double Salts and Related Nanodimensional-Layered Metal Hydroxides on Polymer Thermal Stability, Everson Kandare and Jeanne Hossenlopp

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Structure - property relationships of new polystyrene nanocomposites prepared from initiator-containing layered double hydroxides of zinc aluminum and magnesium aluminum, Charles Manzi-Nshuti, Dan Chen, Shengpei Shu, and Charles Wilkie

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The Effects of Intralayer Metal Composition of Layered Double Hydroxides on Glass Transition, Dispersion, Thermal and Fire Properties of Their PMMA Nanocomposites, Charles Manzi-Nshuti, Dan Chen, Shengpei Su, and Charles Wilkie

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Comparative Study on the Flammability of Polyethylene Modified with Commercial Fire Retardants and a Zinc Aluminum Oleate Layered Double Hydroxide, Charles Manzi-Nshuti, Jeanne Hossenlopp, and Charles Wilkie

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Polymer Nanocomposites Using Zinc Aluminum and Magnesium Aluminum Oleate Layered Double Hydroxides: Effects of LDH Divalent Metals on Dispersion, Thermal, Mechanical and Fire Performance in Various Polymers, Charles Manzi-Nshuti, Ponusa Songtipya, Evangelos Manias, Maria del Mar Jimenez-Gasco, Jeanne Hossenlopp, and Charles Wilkie

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Polymer nanocomposites using zinc aluminum and magnesium aluminum oleate layered double hydroxides: Effects of the polymeric compatibilizer and of composition on the thermal and fire properties of PP/LDH nanocomposites, Charles Manzi-Nshuti, Ponusa Songtipya, Evangelos Manias, Maria del Mar Jimenez-Gasco, Jeanne Hossenlopp, and Charles Wilkie

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The Role of the Trivalent metal in an LDH: Synthesis, Characterization and Fire Properties of Thermally Stable PMMA/LDH Systems, Charles Manzi-Nshuti, Dongyan Wang, Jeanne Hossenlopp, and Charles Wilkie

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Use of Layered Double Hydroxides as Polymer Fire-Retardant Additives: Advantages and Challenges, Charles Manzi-Nshuti, Liying Zhu, Calistor Nyambo, Linjiang Wang, Charles Wilkie, and Jeanne Hossenlopp

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13C-Methyl isocyanide as an NMR probe for cytochrome P450 active site, Christopher R McCullough, Phani Kumar Pullela, Sang-Choul Im, Lucy Waskell, and Daniel Sem

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Mutation of H63 and its Catalytic Affect on the Methionine Aminopeptidase from Escherichia coli, Sanghamitra Mitra, Brian Bennett, and Richard C. Holz

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Analyzing the Binding of Co(II)-specific Inhibitors to the Methionyl Aminopeptidases from Escherichia coli and Pyrococcus furiosus, Sanghamitra Mitra, George Sheppard, Jieyi Wang, Brian Bennett, and Richard C. Holz

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Fire Retardancy in 2009, Gordon L. Nelson, Alexander B. Morgan, and Charles Wilkie

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Does organic modification of layered double hydroxides improve the fire performance of PMMA?, Calistor Nyambo, Dan Chen, Shengpei Shu, and Charles Wilkie

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Variation of benzyl anions in MgAl-layered double hydroxides: Fire and thermal properties in PMMA, Calistor Nyambo, Dan Chen, Shengpei Shu, and Charles Wilkie

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Thermal stability and flammability characteristics of ethylene vinyl acetate (EVA) composites blended with a phenyl phosphonate-intercalated layered double hydroxide (LDH), melamine polyphosphate and/or boric acid, Calistor Nyambo, Everson Kandare, and Charles Wilkie

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Will Layered Double Hydroxides Give Nanocomposites with Polar or Non-polar Polymers?, Calistor Nyambo, Dongyan Wang, and Charles Wilkie

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Layered double hydroxides intercalated with borate anions: Fire and thermal properties in ethylene vinyl acetate copolymer, Calistor Nyambo and Charles Wilkie

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Substrate Induced Structural and Dynamics Changes in Human Phosphomevalonate Iinase and Implications for Mechanism, Andrew Lawrence Olson, Huili Yao, Timothy J. Herdendorf, Henry M. Miziorko, Supa Hannongbua, Patchareenat Saparpakom, Sheng Cai, and Daniel Sem

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Combination of Carbon Nanotubes with Fire Retardants: the Thermal and Fire Properties of Polystyrene Nanocomposites, Florentina Tutunea and Charles Wilkie

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Fire retardancy of bis[2-(methacryloyloxy)ethyl] phosphate modified poly(methyl methacrylate) nanocomposites containing layered double hydroxide and montmorillonite, Linjiang Wang, Shengpei Shu, Dan Chen, and Charles Wilkie

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Variation of anions in layered double hydroxides: Effects on dispersion and fire properties, Linjiang Wang, Shengpei Shu, Dan Chen, and Charles Wilkie

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Flammability Properties of Polymer Nanocomposites, Charles Wilkie and Jin Zhu

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Scope and Mechanistic Investigations on the Solvent-Controlled Regio- and Stereoselective Formation of Enol Esters from the Ruthenium-Catalyzed Coupling Reaction of Terminal Alkynes and Carboxylic Acids, Chae S. Yi and Ruili Gao

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Aqueous Phase C-H Bond Oxidation Reaction of Arylalkanes Catalyzed by a Water-Soluble Cationic Ru(III) Complex [(pymox-Me2)2RuCl2]+BF4-, Chae S. Yi, Ki Hyeok Kwon, and Do W. Lee

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Efficient Dehydrogenation of Amines and Carbonyl Compounds Catalyzed by a Tetranuclear Ruthenium-μ-oxo-μ-hydroxo-hydride Complex, Chae S. Yi and Do W. Lee

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Regioselective Intermolecular Coupling Reaction of Arylketones and Alkenes Involving C-H Bond Activation Catalyzed by an in Situ Formed Cationic Ruthenium-Hydride Complex, Chae S. Yi and Do W. Lee

Submissions from 2008

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2,9-Bis(1,3-benzothia­zol-2-yl)-1,10-phenanthroline Dichloro­methane Disolvate, Jesmin Akther, Sergey Lindeman, and Mohammad Rezaul Karim

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Thermal Stability and Degradation Kinetics of Polystyrene/Organically-Modified Montmorillonite Nanocomposites, Grace Chigwada, Everson Kandare, Dongyan Wang, Stephen Majoni, Darlington Mlambo, Charles A. Wilkie, and Jeanne M. Hossenlopp

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Resonance Raman Characterization of the Peroxo and Hydroperoxo Intermediates in Cytochrome P450, Ilia G. Denisov, Piotr J. Mak, Thomas M. Makris, Stephen G. Sligar, and James R. Kincaid

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Transparent and flame retardant PMMA nanocomposites, Seogjun Kim and Charles Wilkie

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Synthetic studies directed toward amphidinol 2: elucidation of the relative configuration of the C1–C10 fragment, Praveen Kommana, Seung Won Chung, and William Donaldson

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Defining Resonance Raman Spectral Responses to Substrate Binding by Cytochrome P450 from Pseudomonas putida, Piotr J. Mak, Daniel Kaluka, Munyaradzi Edith Manyumwa, Haiqing Zhang, Tianjing Deng, and James R. Kincaid

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Resonance Raman Spectroscopic Studies of Hydroperoxo Derivatives of Cobalt-substituted Myoglobin, Piotr J. Mak and James R. Kincaid

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Fire Retardancy of Melamine and Zinc Aluminum Layered Double Hydroxide in Poly(methyl Methacrylate), Charles Manzi-Nshuti, Jeanne Hossenlopp, and Charles Wilkie

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Aluminum-containing Layered Double Hydroxides: the Thermal, Mechanical, and Fire Properties of (Nano)composites of Poly(methyl Methacrylate), Charles Manzi-Nshuti, Dongyan Wang, Jeanne Hossenlopp, and Charles Wilkie

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Analyzing the Catalytic Role of Asp97 in the Methionine Aminopeptidase from Escherichia coli, Sanghamitra Mitra, Kathleen M. Job, Lu Meng, Brian Bennett, and Richard C. Holz

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First-Row Transition-Metal Complexes of a New Pentadentate Ligand, α,α,α′,α′-Tetra(pyrazolyl)lutidine, Tyler James Morin, Brian Bennett, Sergey V. Lindeman, and James R. Gardinier

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Flame-retarded Polystyrene: Investigating Chemical Interactions between Ammonium Polyphosphate and MgAl Layered Double Hydroxide, Calistor Nyambo, Everson Kandare, Dongyan Wang, and Charles Wilkie

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Effect of MgAl-layered double hydroxide exchanged with linear alkyl carboxylates on fire-retardancy of PMMA and PS, Calistor Nyambo, Ponusa Songtipya, Evangelos Manias, Maria del Mar Jimenez-Gasco, and Charles Wilkie

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Global Conformational Dynamics in Ras, Casey O'Connor and Evgueni Kovriguine

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Reactivity of (2-alkenyl-3-pentene-1,5-diyl)iron complexes: preparation of functionalized vinylcyclopropanes and cycloheptadienes, Rajesh K. Pandey, Lizhu Wang, Nathaniel J Wallock, Sergey Lindeman, and William Donaldson

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HET acid based oligoesters – TGA/FTIR studies, Thangamani Rajkumar, Chinnaswamy Thangavel Vijayakumar, Palanichamy Sivasamy, and Charles Wilkie

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Analyzing the Catalytic Mechanism of the Fe-Type Nitrile Hydratase from Comamonas testosteroni Ni1, Saroja Rao and Richard C. Holz

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Bis[(dimethyl-λ4-sulfanylidene)oxonium] hexabromidotellurate(IV) dimethyl sulfoxide disolvate, Martin D. Rudd, Gregory Kokke, and Sergey V. Lindeman

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Resonance Raman Interrogation of the Consequences of Heme Rotational Disorder in Myoglobin and its Ligated Derivatives, Freeborn Rwere, Piotr J. Mak, and James R. Kincaid

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Nanocomposites I. Current Developments in Nanocomposites as Novel Fire Retardants, Charles Wilkie and Alexander B. Morgan

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Formation of Bicyclic Pyrroles from the Catalytic Coupling Reaction of 2,5-disubstituted Pyrroles with Terminal Alkynes, Involving the Activation of Multiple C-H bonds, Chase S. Yi and Jie Zhang

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Polymerically Modified Layered Silicates: An Effective Route to Nanocomposites, Jinguo Zhang, Evangelos Manias, and Charles Wilkie

Submissions from 2007

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Chemistry and Biology of Streptogramin A Antibiotics, Fahim Ahmed and William Donaldson

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Generation of molecular complexity from cyclooctatetraene: synthesis of a protected 2-(3′-carboxy-2′-benzoylcyclopentyl)glycine, Subhabrata Chaudhury, Sergey Lindeman, and William Donaldson

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Preparation, Characterization and Reactivity of (3-Methylpentadienyl)iron(1+) Cations, Subhabrata Chaudhury, Shukun Li, Dennis W. Bennett, Tasneem Siddiquee, Daniel T. Haworth, and William Donaldson

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Revealing Nano-confinement in Degradation and Relaxation Studies of Two Structurally Different Polystyrene-Clay Systems, Kai Chen, Charles A. Wilkie, and Sergey Vyazovkin

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Enhanced Fire Retardancy of Vinyl Ester Resins by Combination of Additives, Grace Chigwada and Charles Wilkie

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The Influence of Carbon Nanotubes, Organically Modified Montmorillonites and Layered Double Hydroxides on the Thermal Degradation and Fire Retardancy of Polyethylene, Ethylene-Vinyl Acetate Copolymer and Polystyrene, Marius C. Costache, Matthew Heidecker, Evangelos Manias, Giovanni Camino, Alberto Frache, Gunter Beyer, Rakesh K. Gupta, and Charles Wilkie

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Benzimidazolium Surfactants for Modification of Clays for Use with Styrenic Polymers, Marius C. Costache, Matthew Heidecker, Evangelos Manias, Rakesh K. Gupta, and Charles Wilkie

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Resonance Raman Detection of the Hydroperoxo Intermediate in the Cytochrome P450 Enzymatic Cycle, Piotr J. Mak, Ilia G. Denisov, Doreen Victoria, Thomas M. Makris, Tianjing Deng, Stephen G. Sligar, and James R. Kincaid

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Ferrocene and Ferrocenium Modified Clays and Their Styrene and EVA Composites, Charles Manzi-Nshuti and Charles Wilkie

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Unraveling the Catalytic Mechanism of Nitrile Hydratases, Sanghamitra Mitra and Richard C. Holz

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Practical Issues and Future Trends in Polymer Nanocomposite Flammability Research, Alexander B. Morgan and Charles Wilkie

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13C NMR Analysis of Biologically Produced Pyrene Residues by Mycobacterium sp. KMS in the Presence of Humic Acid, J. Karl C. Nieman, Richard C. Holz, and Ronald C. Sims

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Conserved Amino Acids in Each Subunit of the Heteroligomeric tRNA m1A58 Mtase from Saccharomyces cerevisiae Contribute to tRNA Binding, Sarah G. Ozanick, Janusz M. Bujnicki, Daniel Sem, and James T. Anderson

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Synthesis of Cyclopropanes via Organoiron Methodology: Stereoselective Preparation of Bi(cyclopropyl)s, Rajesh K. Pandey, Sergey Lindeman, and William Donaldson

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The Voltammetric Study of the Reduction of Tetraalkylammonium Perchlorate by Fe(TPP)2-, Michael Ryan and Chathra Shirani De Silva

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Use of Factor Analysis in Multi‐Electron Spectroelectrochemistry, Michael D. Ryan and Robert L. Keesey

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Synthesis of Cyclopropanes via Organoiron Methodology: Preparation of rac-Dysibetaine Cpa, Tasneem A. Siddiquee, Julie Lukesh, Sergey Sergey Lindeman, and William A. Donaldson

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Cycloaddition Reactions of Phthalimide Substituted Cyclic Polyenes with Heteroatom Dienophiles, Stephen S. Templin, Nathaniel J. Wallock, Daniel T. Haworth, William A. Donaldson, Dennis W. Bennett, and Tasneem Siddiquee

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Mechanism of Rate-Limiting Motions in Enzyme Function, Eric D. Watt, Hiroko Shimada, Evgueni Kovriguine, and J. Patrick Loria

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Intercalation Compounds and Clay Nanocomposites, Jin Zhu and Charles A. Wilkie

Submissions from 2006

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Synergistic Use of Compound Properties and Docking Scores in Neural Network Modeling of CYP2D6 Binding: Predicting Affinity and Conformational Sampling, Peter S. Bazeley, Sridevi Prithivi, Craig Struble, Richard J. Povinelli, and Daniel Sem

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Crystal and molecular structure of bis(8-phenylmenthyl) 2-(2-methyl-5-oxo-3-cyclohexen-1-yl)propandioate, C42H54O5• CH3CN, Dennis W. Bennett, Tasneem A. Siddiquee, Daniel T. Haworth, Subhabrata Chaudhury, and William Donaldson

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Nucleophilic Addition to (3-Methylpentadienyl)iron(1+) Cations: Counterion Control of Regioselectivity; Application to the Enantioselective Synthesis of 4,5-Disubstituted Cyclohexenones, Subhabrata Chaudhury and William Donaldson

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Synthetic studies directed toward the proposed structure for heteroscyphic acid A, Subhabrata Chaudhury, Shukun Li, and William Donaldson

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Styrenic Nanocomposites Prepared using a Novel Biphenyl-Containing Clay, Grace Chigwada, Dongyan Wang, David D. Jiang, and Charles Wilkie

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Polystyrene Nanocomposites Based on Quinolinium and Pyridinium Surfactants, Grace Chigwada, Dongyan Wang, and Charles Wilkie

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Preparation and Characterization of Poly(Ethylene Terephtalate)/Clay Nanocomposites by Melt Blending using Thermally Stable Surfactants, Marius Cristian Costache, Matthew Heidecker, Evangelos Manias, and Charles Wilkie

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Fire Retardancy of Polyureas, Marius Cristian Costache, Eric M. Kanugh, Charles Wilkie, and Usman Sorathia

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The Thermal Degradation of Poly(methyl methacrylate) Nanocomposites with Montmorillonite, Layered Double Hydroxides and Carbon Nanotubes, Marius C. Costache, Dongyan Wang, Matthew Heidecker, Evangelos Manias, and Charles Wilkie

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The High-Resolution Structures of the Neutral and the Low pH Crystals of Aminopeptidase from Aeromonas proteolytica, William Desmarais, David L. Bienvenue, Krzysztof P. Bzymek, Gregory A. Petsko, Dagmar Ringe, and Richard C. Holz

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The Proteomics of N-terminal Methionine Cleavage, Frédéric Frottin, Aude Martinez, Philippe Peynot, Sanghamitra Mitra, Richard C. Holz, Carmela Giglione, and Thierry Meinnel

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Additional evidence for the migration of clay upon heating of clay–polypropylene nanocomposites from X-ray photoelectron spectroscopy (XPS), JIanwei Hao, Menachem Lewin, Charles Wilkie, and Jiangqi Wang

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Applications of Acoustic Wave Devices for Sensing in Liquid Environments, Jeanne Hossenlopp

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Nanostructured Layered Copper Hydroxy Dodecyl Sulfate: A Potential Fire Retardant for Poly(vinyl Ester) (PVE), Everson Kandare, Grace Chigwada, Dongyan Wang, Charles Wilkie, and Jeanne Hossenlopp

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Probing Synergism, Antagonism, and Additive Effects in Poly(vinyl Ester) (PVE) Composites with Fire Retardants, Everson Kandare, Grace Chigwada, Dongyan Wang, Charles Wilkie, and Jeanne Hossenlopp

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Thermal Stability and Degradation Kinetics of Poly(methyl Methacrylate)/Layered Copper Hydroxy Methacrylate Composites, Everson Kandare, Hongmei Deng, Dongyan Wang, and Jeanne Hossenlopp

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Thermal Degradation of Acetate-Intercalated Hydroxy Double and Layered Hydroxy Salts, Everson Kandare and Jeanne Hossenlopp

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NMR Studies of Escherichia Coli Acyl Carrier Protein: Dynamic and Structural Differences of the Apo- and Holo-forms, Yangmee Kim, Evgueni Kovriguine, and Ziad Eletr

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Faithful Estimation of Dynamics Parameters from CPMG Relaxation Dispersion Measurements, Evgueni Kovriguine, James G. Kempf, Michael J. Grey, and J. Patrick Loria

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Characterization of the Transition State of Functional Enzyme Dynamics, Evgueni Kovriguine and J. Patrick Loria

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Enzyme Dynamics Along the Reaction Coordinate: Critical Role of a Conserved Residue, Evgueni Kovriguine and J. Patrick Loria