The Chemistry Faculty Research and Publications Series is comprised of books and articles published by Marquette University's chemistry faculty.

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Submissions from 2009

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Layered double hydroxides intercalated with borate anions: Fire and thermal properties in ethylene vinyl acetate copolymer, Calistor Nyambo and Charles Wilkie

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Substrate Induced Structural and Dynamics Changes in Human Phosphomevalonate Iinase and Implications for Mechanism, Andrew Lawrence Olson, Huili Yao, Timothy J. Herdendorf, Henry M. Miziorko, Supa Hannongbua, Patchareenat Saparpakom, Sheng Cai, and Daniel Sem

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Combination of Carbon Nanotubes with Fire Retardants: the Thermal and Fire Properties of Polystyrene Nanocomposites, Florentina Tutunea and Charles Wilkie

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Fire retardancy of bis[2-(methacryloyloxy)ethyl] phosphate modified poly(methyl methacrylate) nanocomposites containing layered double hydroxide and montmorillonite, Linjiang Wang, Shengpei Shu, Dan Chen, and Charles Wilkie

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Variation of anions in layered double hydroxides: Effects on dispersion and fire properties, Linjiang Wang, Shengpei Shu, Dan Chen, and Charles Wilkie

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Flammability Properties of Polymer Nanocomposites, Charles Wilkie and Jin Zhu

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Scope and Mechanistic Investigations on the Solvent-Controlled Regio- and Stereoselective Formation of Enol Esters from the Ruthenium-Catalyzed Coupling Reaction of Terminal Alkynes and Carboxylic Acids, Chae S. Yi and Ruili Gao

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Aqueous Phase C-H Bond Oxidation Reaction of Arylalkanes Catalyzed by a Water-Soluble Cationic Ru(III) Complex [(pymox-Me2)2RuCl2]+BF4-, Chae S. Yi, Ki Hyeok Kwon, and Do W. Lee

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Efficient Dehydrogenation of Amines and Carbonyl Compounds Catalyzed by a Tetranuclear Ruthenium-μ-oxo-μ-hydroxo-hydride Complex, Chae S. Yi and Do W. Lee

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Regioselective Intermolecular Coupling Reaction of Arylketones and Alkenes Involving C-H Bond Activation Catalyzed by an in Situ Formed Cationic Ruthenium-Hydride Complex, Chae S. Yi and Do W. Lee

Submissions from 2008

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2,9-Bis(1,3-benzothia­zol-2-yl)-1,10-phenanthroline Dichloro­methane Disolvate, Jesmin Akther, Sergey Lindeman, and Mohammad Rezaul Karim

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Thermal Stability and Degradation Kinetics of Polystyrene/Organically-Modified Montmorillonite Nanocomposites, Grace Chigwada, Everson Kandare, Dongyan Wang, Stephen Majoni, Darlington Mlambo, Charles A. Wilkie, and Jeanne M. Hossenlopp

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Resonance Raman Characterization of the Peroxo and Hydroperoxo Intermediates in Cytochrome P450, Ilia G. Denisov, Piotr J. Mak, Thomas M. Makris, Stephen G. Sligar, and James R. Kincaid

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Transparent and flame retardant PMMA nanocomposites, Seogjun Kim and Charles Wilkie

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Synthetic studies directed toward amphidinol 2: elucidation of the relative configuration of the C1–C10 fragment, Praveen Kommana, Seung Won Chung, and William Donaldson

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Defining Resonance Raman Spectral Responses to Substrate Binding by Cytochrome P450 from Pseudomonas putida, Piotr J. Mak, Daniel Kaluka, Munyaradzi Edith Manyumwa, Haiqing Zhang, Tianjing Deng, and James R. Kincaid

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Resonance Raman Spectroscopic Studies of Hydroperoxo Derivatives of Cobalt-substituted Myoglobin, Piotr J. Mak and James R. Kincaid

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Fire Retardancy of Melamine and Zinc Aluminum Layered Double Hydroxide in Poly(methyl Methacrylate), Charles Manzi-Nshuti, Jeanne Hossenlopp, and Charles Wilkie

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Aluminum-containing Layered Double Hydroxides: the Thermal, Mechanical, and Fire Properties of (Nano)composites of Poly(methyl Methacrylate), Charles Manzi-Nshuti, Dongyan Wang, Jeanne Hossenlopp, and Charles Wilkie

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Analyzing the Catalytic Role of Asp97 in the Methionine Aminopeptidase from Escherichia coli, Sanghamitra Mitra, Kathleen M. Job, Lu Meng, Brian Bennett, and Richard C. Holz

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First-Row Transition-Metal Complexes of a New Pentadentate Ligand, α,α,α′,α′-Tetra(pyrazolyl)lutidine, Tyler James Morin, Brian Bennett, Sergey V. Lindeman, and James R. Gardinier

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Flame-retarded Polystyrene: Investigating Chemical Interactions between Ammonium Polyphosphate and MgAl Layered Double Hydroxide, Calistor Nyambo, Everson Kandare, Dongyan Wang, and Charles Wilkie

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Effect of MgAl-layered double hydroxide exchanged with linear alkyl carboxylates on fire-retardancy of PMMA and PS, Calistor Nyambo, Ponusa Songtipya, Evangelos Manias, Maria del Mar Jimenez-Gasco, and Charles Wilkie

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Global Conformational Dynamics in Ras, Casey O'Connor and Evgueni Kovriguine

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Reactivity of (2-alkenyl-3-pentene-1,5-diyl)iron complexes: preparation of functionalized vinylcyclopropanes and cycloheptadienes, Rajesh K. Pandey, Lizhu Wang, Nathaniel J Wallock, Sergey Lindeman, and William Donaldson

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HET acid based oligoesters – TGA/FTIR studies, Thangamani Rajkumar, Chinnaswamy Thangavel Vijayakumar, Palanichamy Sivasamy, and Charles Wilkie

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Analyzing the Catalytic Mechanism of the Fe-Type Nitrile Hydratase from Comamonas testosteroni Ni1, Saroja Rao and Richard C. Holz

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Bis[(dimethyl-λ4-sulfanylidene)oxonium] hexabromidotellurate(IV) dimethyl sulfoxide disolvate, Martin D. Rudd, Gregory Kokke, and Sergey V. Lindeman

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Resonance Raman Interrogation of the Consequences of Heme Rotational Disorder in Myoglobin and its Ligated Derivatives, Freeborn Rwere, Piotr J. Mak, and James R. Kincaid

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Nanocomposites I. Current Developments in Nanocomposites as Novel Fire Retardants, Charles Wilkie and Alexander B. Morgan

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Formation of Bicyclic Pyrroles from the Catalytic Coupling Reaction of 2,5-disubstituted Pyrroles with Terminal Alkynes, Involving the Activation of Multiple C-H bonds, Chase S. Yi and Jie Zhang

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Polymerically Modified Layered Silicates: An Effective Route to Nanocomposites, Jinguo Zhang, Evangelos Manias, and Charles Wilkie

Submissions from 2007

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Chemistry and Biology of Streptogramin A Antibiotics, Fahim Ahmed and William Donaldson

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Generation of molecular complexity from cyclooctatetraene: synthesis of a protected 2-(3′-carboxy-2′-benzoylcyclopentyl)glycine, Subhabrata Chaudhury, Sergey Lindeman, and William Donaldson

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Preparation, Characterization and Reactivity of (3-Methylpentadienyl)iron(1+) Cations, Subhabrata Chaudhury, Shukun Li, Dennis W. Bennett, Tasneem Siddiquee, Daniel T. Haworth, and William Donaldson

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Revealing Nano-confinement in Degradation and Relaxation Studies of Two Structurally Different Polystyrene-Clay Systems, Kai Chen, Charles A. Wilkie, and Sergey Vyazovkin

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Enhanced Fire Retardancy of Vinyl Ester Resins by Combination of Additives, Grace Chigwada and Charles Wilkie

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The Influence of Carbon Nanotubes, Organically Modified Montmorillonites and Layered Double Hydroxides on the Thermal Degradation and Fire Retardancy of Polyethylene, Ethylene-Vinyl Acetate Copolymer and Polystyrene, Marius C. Costache, Matthew Heidecker, Evangelos Manias, Giovanni Camino, Alberto Frache, Gunter Beyer, Rakesh K. Gupta, and Charles Wilkie

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Benzimidazolium Surfactants for Modification of Clays for Use with Styrenic Polymers, Marius C. Costache, Matthew Heidecker, Evangelos Manias, Rakesh K. Gupta, and Charles Wilkie

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Resonance Raman Detection of the Hydroperoxo Intermediate in the Cytochrome P450 Enzymatic Cycle, Piotr J. Mak, Ilia G. Denisov, Doreen Victoria, Thomas M. Makris, Tianjing Deng, Stephen G. Sligar, and James R. Kincaid

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Ferrocene and Ferrocenium Modified Clays and Their Styrene and EVA Composites, Charles Manzi-Nshuti and Charles Wilkie

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Unraveling the Catalytic Mechanism of Nitrile Hydratases, Sanghamitra Mitra and Richard C. Holz

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Practical Issues and Future Trends in Polymer Nanocomposite Flammability Research, Alexander B. Morgan and Charles Wilkie

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13C NMR Analysis of Biologically Produced Pyrene Residues by Mycobacterium sp. KMS in the Presence of Humic Acid, J. Karl C. Nieman, Richard C. Holz, and Ronald C. Sims

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Conserved Amino Acids in Each Subunit of the Heteroligomeric tRNA m1A58 Mtase from Saccharomyces cerevisiae Contribute to tRNA Binding, Sarah G. Ozanick, Janusz M. Bujnicki, Daniel Sem, and James T. Anderson

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Synthesis of Cyclopropanes via Organoiron Methodology: Stereoselective Preparation of Bi(cyclopropyl)s, Rajesh K. Pandey, Sergey Lindeman, and William Donaldson

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The Voltammetric Study of the Reduction of Tetraalkylammonium Perchlorate by Fe(TPP)2-, Michael Ryan and Chathra Shirani De Silva

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Use of Factor Analysis in Multi‐Electron Spectroelectrochemistry, Michael D. Ryan and Robert L. Keesey

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Synthesis of Cyclopropanes via Organoiron Methodology: Preparation of rac-Dysibetaine Cpa, Tasneem A. Siddiquee, Julie Lukesh, Sergey Sergey Lindeman, and William A. Donaldson

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Cycloaddition Reactions of Phthalimide Substituted Cyclic Polyenes with Heteroatom Dienophiles, Stephen S. Templin, Nathaniel J. Wallock, Daniel T. Haworth, William A. Donaldson, Dennis W. Bennett, and Tasneem Siddiquee

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Mechanism of Rate-Limiting Motions in Enzyme Function, Eric D. Watt, Hiroko Shimada, Evgueni Kovriguine, and J. Patrick Loria

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Intercalation Compounds and Clay Nanocomposites, Jin Zhu and Charles A. Wilkie

Submissions from 2006

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Synergistic Use of Compound Properties and Docking Scores in Neural Network Modeling of CYP2D6 Binding: Predicting Affinity and Conformational Sampling, Peter S. Bazeley, Sridevi Prithivi, Craig Struble, Richard J. Povinelli, and Daniel Sem

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Crystal and molecular structure of bis(8-phenylmenthyl) 2-(2-methyl-5-oxo-3-cyclohexen-1-yl)propandioate, C42H54O5• CH3CN, Dennis W. Bennett, Tasneem A. Siddiquee, Daniel T. Haworth, Subhabrata Chaudhury, and William Donaldson

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Nucleophilic Addition to (3-Methylpentadienyl)iron(1+) Cations: Counterion Control of Regioselectivity; Application to the Enantioselective Synthesis of 4,5-Disubstituted Cyclohexenones, Subhabrata Chaudhury and William Donaldson

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Synthetic studies directed toward the proposed structure for heteroscyphic acid A, Subhabrata Chaudhury, Shukun Li, and William Donaldson

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Styrenic Nanocomposites Prepared using a Novel Biphenyl-Containing Clay, Grace Chigwada, Dongyan Wang, David D. Jiang, and Charles Wilkie

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Polystyrene Nanocomposites Based on Quinolinium and Pyridinium Surfactants, Grace Chigwada, Dongyan Wang, and Charles Wilkie

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Preparation and Characterization of Poly(Ethylene Terephtalate)/Clay Nanocomposites by Melt Blending using Thermally Stable Surfactants, Marius Cristian Costache, Matthew Heidecker, Evangelos Manias, and Charles Wilkie

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Fire Retardancy of Polyureas, Marius Cristian Costache, Eric M. Kanugh, Charles Wilkie, and Usman Sorathia

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The Thermal Degradation of Poly(methyl methacrylate) Nanocomposites with Montmorillonite, Layered Double Hydroxides and Carbon Nanotubes, Marius C. Costache, Dongyan Wang, Matthew Heidecker, Evangelos Manias, and Charles Wilkie

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The High-Resolution Structures of the Neutral and the Low pH Crystals of Aminopeptidase from Aeromonas proteolytica, William Desmarais, David L. Bienvenue, Krzysztof P. Bzymek, Gregory A. Petsko, Dagmar Ringe, and Richard C. Holz

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The Proteomics of N-terminal Methionine Cleavage, Frédéric Frottin, Aude Martinez, Philippe Peynot, Sanghamitra Mitra, Richard C. Holz, Carmela Giglione, and Thierry Meinnel

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Additional evidence for the migration of clay upon heating of clay–polypropylene nanocomposites from X-ray photoelectron spectroscopy (XPS), JIanwei Hao, Menachem Lewin, Charles Wilkie, and Jiangqi Wang

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Applications of Acoustic Wave Devices for Sensing in Liquid Environments, Jeanne Hossenlopp

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Nanostructured Layered Copper Hydroxy Dodecyl Sulfate: A Potential Fire Retardant for Poly(vinyl Ester) (PVE), Everson Kandare, Grace Chigwada, Dongyan Wang, Charles Wilkie, and Jeanne Hossenlopp

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Probing Synergism, Antagonism, and Additive Effects in Poly(vinyl Ester) (PVE) Composites with Fire Retardants, Everson Kandare, Grace Chigwada, Dongyan Wang, Charles Wilkie, and Jeanne Hossenlopp

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Thermal Stability and Degradation Kinetics of Poly(methyl Methacrylate)/Layered Copper Hydroxy Methacrylate Composites, Everson Kandare, Hongmei Deng, Dongyan Wang, and Jeanne Hossenlopp

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Thermal Degradation of Acetate-Intercalated Hydroxy Double and Layered Hydroxy Salts, Everson Kandare and Jeanne Hossenlopp

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NMR Studies of Escherichia Coli Acyl Carrier Protein: Dynamic and Structural Differences of the Apo- and Holo-forms, Yangmee Kim, Evgueni Kovriguine, and Ziad Eletr

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Faithful Estimation of Dynamics Parameters from CPMG Relaxation Dispersion Measurements, Evgueni Kovriguine, James G. Kempf, Michael J. Grey, and J. Patrick Loria

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Characterization of the Transition State of Functional Enzyme Dynamics, Evgueni Kovriguine and J. Patrick Loria

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Enzyme Dynamics Along the Reaction Coordinate: Critical Role of a Conserved Residue, Evgueni Kovriguine and J. Patrick Loria

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Nanocomposites at Elevated Temperatures: Migration and Structural Changes, Menachem Lewin, E. M. Pearce, Kelle Levon, Abraham Mey-Marom, Mauro Zammarano, Charles Wilkie, and Bok Nam Jang

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A New Colorimetric Assay for Methionyl Aminopeptidases: Examination of the Binding of a New Class of Pseudopeptide Analog Inhibitors, Sanghamitra Mitra, Anna M. Dygas-Holz, Jiri Jiracek, Miroslava Zertova, Lenka Zakova, and Richard C. Holz

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Attachment of Motile Bacterial Cells to Prealigned Holed Microarrays, Sergey Rozhok, Zhifang Fan, Dorjderem Nyamjav, Chang Liu, Chad A. Mirkin, and Richard C. Holz

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The Redox Couple of the Cytochrome c Cyanide Complex: The Contribution of Heme Iron Ligation to the Structural Stability, Chemical Reactivity, and Physiological Behavior of Horse Cytochrome c, Abel Schejter, Michael Ryan, Erica R. Blizzard, Chongyao Zhang, Emanuel Margoliash, and Benjamin A. Feinberg

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Novel Potentiometric and Optical Silver Ion-selective Sensors with Subnanomolar Detection Limits, Zsófia Szigeti, Adam Malon, Tamás Vigassy, Viktor Csokai, Alajos Grün, Katarzyna Wygladacz, Nan Ye, Chao Xu, Vincent J. Chebny, István Bitter, Rajendra Rathore, Eric Bakker, and Ernö Pretsch

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TGA analysis of γ-Irradiated Linear Low Density Polyethylene, Adams Tidjani and Charles Wilkie

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Synthesis of Cyclopropanes via Organoiron Methodology: Preparation and Rearrangement of Divinylcyclopropanes - Studies Directed toward the Synthesis­ of Hydroazulenes, Nathaniel J Wallock, Dennis W. Bennett, Tasneem Siddiquee, Daniel T. Haworth, and William Donaldson

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Fire Properties of Polymer Nanocomposites, Charles Wilkie

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High-Throughput Techniques for the Evaluation of Fire Retardancy, Charles Wilkie, Grace Chigwada, Jeffery W. Gilman Sr., and Richard E. Lyon

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A Review of Recent Work in the Fire Retardancy of Nanocomposites, Charles Wilkie, Xiaoxia Zheng, Grace Chigwada, Marius C. Costache, Bok Nam Jang, and Jinguo Zhang

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Highly Cooperative Tetrametallic Ruthenium-μ-Oxo-μ-Hydroxo Catalyst for the Alcohol Oxidation Reaction, Chae S. Yi, Tonya N. Zeczycki, and Ilia A. Guzei

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Controlled Silylation of Montmorillonite and its Polyethylene Nanocomposites, Jinguo Zhang, Rakesh K. Gupta, and Charles Wilkie

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Styrenic Polymer Nanocomposites Based on an Oligomerically-Modified Clay with High Inorganic Content, Jinguo Zhang, David D. Jiang, Dongyan Wang, and Charles Wilkie

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Fire properties of styrenic polymer–clay nanocomposites based on an oligomerically-modified clay, Jinguo Zhang, David D. Jiang, and Charles Wilkie

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Polyethylene and polypropylene nanocomposites based on a three component oligomerically-modified clay, Jinguo Zhang, David D. Jiang, and Charles Wilkie

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Thermal and Flame Properties of Polyethylene and Polypropylene Nanocomposites Based on an Oligomerically–Modified Clay, Jinguo Zhang, David D. Jiang, and Charles Wilkie

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Fire Retardancy of Polypropylene-Metal Hydroxide Nanocomposites, Jinguo Zhang and Charles Wilkie

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Polyethylene and Polypropylene Nanocomposites Based on Polymerically - Modified Clay Containing Alkylstyrene Units, Jinguo Zhang and Charles Wilkie

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Flammability of styrenic polymer clay nanocomposites based on a methyl methacrylate oligomerically-modified clay, Xiaoxia Zheng, David D. Jiang, Dongyan Wang, and Charles Wilkie

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Polystyrene nanocomposites based on an oligomerically-modified clay containing maleic anhydride, Xiaoxia Zheng, David D. Jiang, and Charles Wilkie

Submissions from 2005

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Development of Organoiron Methodology for the C8-C16 Dienylamine Segment of the Streptogramin Antibiotics, Fahim Ahmed, Yeyu Cao, and William Donaldson

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Kinetic, Spectroscopic, and X-ray Crystallographic Characterization of the Functional E151H Aminopeptidase from Aeromonas proteolytica, Krzysztof P. Bzymek, Aaron Moulin, Sabina I. Swierczek, Dagmar Ringe, Gregory A. Petsko, Brian Bennett, and Richard C. Holz

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Fire Retardancy of Vinyl Ester Nanocomposites: Synergy with Phosphorus-Based Fire Retardants, Grace Chigwada, Panchatapa Jash, David D. Jiang, and Charles Wilkie

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Synergy Between Nanocomposite Formation and Low Levels of Bromine on Fire Retardancy in Polystyrenes, Grace Chigwada, Panchatapa Jash, David D. Jiang, and Charles Wilkie

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Fire Retardancy of Polystyrene Nanocomposites Using Naphthenate-Containing Clays, Grace Chigwada, David D. Jiang, and Charles Wilkie

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Polystyrene Nanocomposites based on Carbazole-Containing Surfactants, Grace Chigwada, David D. Jiang, and Charles Wilkie

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EPR and X-ray Crystallographic Characterization of the Product-Bound Form of the MnII-Loaded Methionyl Aminopeptidase from Pyrococcus furiosus, Alicja J. Copik, Boguslaw P. Nocek, Sabina I. Swierczek, Shane Ruebush, Se Bok Jang, Lu Meng, Ventris M. D'Souza, John W. Peters, Brian Bennett, and Richard C. Holz