A Simple Kinetic Analysis of Syngas During Steam Hydrogasification of Biomass Using a Novel Inverted Batch Reactor with Instant High Pressure Feeding

Authors

Xin Fan, University of California, Riverside
Zhongzhe Liu, Marquette UniversityFollow
Joseph M. Norbeck, University of California, Riverside
Chan S. Park, University of California, Riverside

Document Type

Article

Language

eng

Format of Original

7 p.

Publication Date

1-2016

Publisher

Elsevier

Source Publication

Bioresource Technology

Source ISSN

0960-8524

Original Item ID

doi: 10.1016/j.biortech.2015.10.094; PubMed Central, PMID: 26562689

Abstract

A newly designed inverted batch reactor equipped with a pressure-driven feeding system was built for investigating the kinetics of syngas during the steam hydrogasification (SHR) of biomass. The system could instantly load the feedstock into the reactor at high temperature and pressure, which simulated the way to transport the feedstock into a hot and pressurized gasifier. Experiments were conducted from 600 °C to 700 °C. The inverted reactor showed very high heating rate by enhancing the carbon conversion and syngas production. The kinetic study showed that the rates of CH₄, CO and CO₂ formation during SHR were increased when the gasification temperature went up. SHR had comparatively lower activation energy for CH₄ production. The activation energies of CH₄, CO and CO₂ during SHR were 42.8, 51.8 and 14 kJ/mol, respectively.

Comments

Accepted version. Bioresource Technology, Vol. 200 (January 2016): 731-737. DOI. © 2016 Elsevier Ltd. Used with permission.

Recommended Citation

Fan, Xin; Liu, Zhongzhe; Norbeck, Joseph M.; and Park, Chan S., "A Simple Kinetic Analysis of Syngas During Steam Hydrogasification of Biomass Using a Novel Inverted Batch Reactor with Instant High Pressure Feeding" (2016). Civil and Environmental Engineering Faculty Research and Publications. 125.
https://epublications.marquette.edu/civengin_fac/125