e-Publications@Marquette

Title

A Shortened Synthesis of Optically Pure Tricarbonyl[methyl (2E,4E)-6-oxo-2,4-hexadienoate]Iron Leading to Improved Yield

Authors

Rajesh K. Pandey, Marquette University
Sergey Lindeman, Marquette UniversityFollow
William A. Donaldson, Marquette UniversityFollow

Grant Title

Natural Products Synthesis via Organoiron Methodology

Document Type

Article

Publication Date

2010

Source Publication

Archive for Organic Chemistry

Source ISSN

1551-7012

Abstract

The (+)- and (–)-enantiomers of tricarbonyl[methyl (2E,4E)-6-oxo-2,4-hexadienoate]iron are prepared in 4 steps from commercially available hexadienal (26% and 25% yields, respectively).

Document Rights and Citation of Original

Published version. Archive for Organic Chemistry, Volume IV (2010), Permalink. Used with permission.

Material from ARKIVOC may be stored and used electronically free of charge by any individual or organization but resale of electronically stored material requires permission of the Publisher.

Recommended Citation

Pandey, Rajesh K.; Lindeman, Sergey; and Donaldson, William A., "A Shortened Synthesis of Optically Pure Tricarbonyl[methyl (2E,4E)-6-oxo-2,4-hexadienoate]Iron Leading to Improved Yield" (2010). Natural Products Synthesis via Organoiron Methodology. 6.
https://epublications.marquette.edu/data_nps/6