A ‘Metallic Tape’ Stabilized by an Unprecedented μ₅-κ²,κ²,κ²,κ¹,κ¹-) Scorpionate Binding Mode

Authors

James R. Gardinier, Marquette UniversityFollow
Rosalice M. Silva, Marquette University
Chengeto Gwengo, Marquette University
Sergey V. Lindeman, Marquette UniversityFollow

Document Type

Article

Language

eng

Publication Date

2007

Publisher

Royal Society of Chemistry

Source Publication

Chemical Communications

Source ISSN

1359-7345

Abstract

The Janus scorpionate ligand, tris(mercaptothiadiazolyl)borate, exhibits extraordinary coordination capacity and versatility, binding from two up to five metal cations as demonstrated by its thallium(I) salt, a compound that serves as a model for metal–surface binding.

Comments

Published version. Chemical Communications No. 15 (2007): 1524-1526. DOI. © 2007 Royal Society of Chemistry. Used with permission.

Recommended Citation

Gardinier, James R.; Silva, Rosalice M.; Gwengo, Chengeto; and Lindeman, Sergey V., "A ‘Metallic Tape’ Stabilized by an Unprecedented μ₅-κ²,κ²,κ²,κ¹,κ¹-) Scorpionate Binding Mode" (2007). Chemistry Faculty Research and Publications. 636.
https://epublications.marquette.edu/chem_fac/636