A ‘Metallic Tape’ Stabilized by an Unprecedented μ5-κ2,κ2,κ2,κ1,κ1-) Scorpionate Binding Mode
Royal Society of Chemistry
The Janus scorpionate ligand, tris(mercaptothiadiazolyl)borate, exhibits extraordinary coordination capacity and versatility, binding from two up to five metal cations as demonstrated by its thallium(I) salt, a compound that serves as a model for metal–surface binding.
Gardinier, James R.; Silva, Rosalice M.; Gwengo, Chengeto; and Lindeman, Sergey V., "A ‘Metallic Tape’ Stabilized by an Unprecedented μ5-κ2,κ2,κ2,κ1,κ1-) Scorpionate Binding Mode" (2007). Chemistry Faculty Research and Publications. 636.