Macrobicyclic d-Metal Tris-Dioximates Obtained by Cross-linking with p-Block Elements. XV. Crystal and Molecular Structures of Two Macrobiocyclic Tin-containing Cobalt(III) Tris-Dioximates

Authors

Sergey Lindeman, Marquette UniversityFollow
Yuri T. Struchkov, Institute of Organoelement CompoundsFollow
Yan Z. Voloshin, Karpov Institute of Physical ChemistryFollow

Document Type

Article

Language

eng

Publication Date

1995

Publisher

Taylor & Francis

Source Publication

Journal of Coordination Chemistry

Source ISSN

0095-8972

Abstract

The structure of the tin-containing clathrochelates cyclohexadione-1,2-dioximate (NBu₄)[CoNx₃ (SnCl₃)₂] (A) and dimethylglioximate (NBu₄)[CoDm₃(SnBr₃)₂]·H₂O (B) have been determined by X-ray methods. Crystal data: (A) is orthorhombic, space group P2₁2₁2₁ a = 16.566(4), b = 16.551(4), c = 16.560(4)Å, Z = 4; (B) is orthorhombic, space group Pca2₁, a = 16.271(3), b = 15.337(3), c = 18.572(4)Å, Z = 4. The cobalt(III) atoms are encapsulated by the clathrochelate ligands and surrounded by a distorted octahedral coordination polyhedron.

Comments

Journal of Coordination Chemistry, Vol. 34, No. 3 (1995): 203-213. DOI.

Sergei V. Lindeman as affiliated with Nesmeyanov Institute of Organoelement Compounds, Moscow, Russia at the time of publication.

Recommended Citation

Lindeman, Sergey; Struchkov, Yuri T.; and Voloshin, Yan Z., "Macrobicyclic d-Metal Tris-Dioximates Obtained by Cross-linking with p-Block Elements. XV. Crystal and Molecular Structures of Two Macrobiocyclic Tin-containing Cobalt(III) Tris-Dioximates" (1995). Chemistry Faculty Research and Publications. 660.
https://epublications.marquette.edu/chem_fac/660