Title

Novel Class of Transition Metal Coordination Compounds with Macrocyclic Organosiloxanolate Ligands; their Synthesis and Crystal Structure

Document Type

Article

Language

eng

Publication Date

1-1992

Publisher

Elsevier

Source Publication

Journal of Organometallic Chemistry

Source ISSN

0022-328X

Abstract

Interaction of sodium organosiloxanolates with transition metal chlorides leads to the formation of a novel class of coordination compounds, polymetallaorganosiloxanolates (PMOS) {SiPh(O)-O}n−n M12" role="presentation">n−x2+Nan (M = Mn, Co, Ni, Cu), whose structure is elucidated by an X-ray diffraction study.

Comments

Journal of Organometallic Chemistry, Vol 423, No. 3 (January 28, 1992): 351-360. DOI.

Sergey Lindeman was affiliated with A.N. Nesmeyanov Institute of Organoelement Compounds of the Academy of Sciences of the USSR at the time of publication.

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