Novel Class of Transition Metal Coordination Compounds with Macrocyclic Organosiloxanolate Ligands; their Synthesis and Crystal Structure

Authors

V. A. Igonin, A.N. Nesmeyanov Institute of Organoelement Compounds of the Academy of Sciences of the USSRFollow
Olga I. Shchegolikhina, A.N. Nesmeyanov Institute of Organoelement Compounds of the Academy of Sciences of the USSRFollow
Sergey Lindeman, Marquette UniversityFollow
M. M. Levitsky, A.N. Nesmeyanov Institute of Organoelement Compounds of the Academy of Sciences of the USSR
Yuri T. Struchkov, Nesmeyanov Institute of Organoelement CompoundsFollow
Alexandr A. Zhdanov, A.N. Nesmeyanov Institute of Organoelement Compounds of the Academy of Sciences of the USSRFollow

Document Type

Article

Language

eng

Publication Date

1-1992

Publisher

Elsevier

Source Publication

Journal of Organometallic Chemistry

Source ISSN

0022-328X

Abstract

Interaction of sodium organosiloxanolates with transition metal chlorides leads to the formation of a novel class of coordination compounds, polymetallaorganosiloxanolates (PMOS) {SiPh(O)-O}ⁿ⁻_n M_{12" role="presentation">}n−x²⁺Na_n (M = Mn, Co, Ni, Cu), whose structure is elucidated by an X-ray diffraction study.

Comments

Journal of Organometallic Chemistry, Vol 423, No. 3 (January 28, 1992): 351-360. DOI.

Sergey Lindeman was affiliated with A.N. Nesmeyanov Institute of Organoelement Compounds of the Academy of Sciences of the USSR at the time of publication.

Recommended Citation

Igonin, V. A.; Shchegolikhina, Olga I.; Lindeman, Sergey; Levitsky, M. M.; Struchkov, Yuri T.; and Zhdanov, Alexandr A., "Novel Class of Transition Metal Coordination Compounds with Macrocyclic Organosiloxanolate Ligands; their Synthesis and Crystal Structure" (1992). Chemistry Faculty Research and Publications. 716.
https://epublications.marquette.edu/chem_fac/716