Title

Reactivity of (3-chloro-2-methylenecycloalkyl)palladium Chloride Dimers: Coupling with Phenyl Nucleophiles

Document Type

Article

Language

eng

Publication Date

9-18-1990

Publisher

Elsevier

Source Publication

Journal of Organometallic Chemistry

Source ISSN

0022-328X

Abstract

Reaction of the (3-chloro-2-methylenecycloalkyl)palladium complexes (1) with sodium tetraphenylborate proceeds via coupling at either the exocyclic or endocyclic terminus to afford phenyl substituted π-allyl complexes 5 and/or 11. The regioselectivity of this coupling reaction is somewhat dependent on ring size. The new π-allyl complexes 5/11 can further undergo cleavage reaction or nucleophilic addition.

Comments

Journal of Organometallic Chemistry, Vol. 395, No. 1 (September 18, 1990): 113-120. DOI.

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