Title

Reactivity of Cross-Conjugated (pentadienyl)iron Cations: Formation of Diene and Trimethylenemethane Complexes

Document Type

Article

Language

eng

Publication Date

11-25-1991

Publisher

Elsevier

Source Publication

Tetrahedron Letters

Source ISSN

0040-4039

Abstract

The title cations can be generated from the BF3.Et2O mediated ionization of (acetoxymethylene-butadiene)Fe(CO)3 complexes. The cation reacts with carbon nucleophiles predominantly at C-4 to afford (trimethylenemethane)Fe(CO)3 products.

The title cations can be generated from the BF3. Et2O mediated ionization of (acetoxymethylenebutadiene) Fe (CO)3 complexes. The cations react with carbon nucleophiles predominantly at C-4 to afford (trimethylenemethane) Fe (CO)3 products.

Comments

Tetrahedron Letters, Vol. 32, No. 48 (November 25, 1991): 7047-7050. DOI.

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