X-ray Structure of mer-[Mo(CO)₃(PPh₃)(κ²-dppm)]

Authors

Shishir Ghosh, Jahangirnagar UniversityFollow
Shariff E. Kabir, Jahangirnagar University
Faranza K. Camellia, Jahangirnagar University
Md. Kamal Hossain, Jahangirnagar University
Daniel T. Haworth, Marquette UniversityFollow
Sergey V. Lindeman, Marquette UniversityFollow
Tasneem A. Siddiquee, Tennessee State UniversityFollow
Dennis W. Bennett, University of Wisconsin - MilwaukeeFollow

Document Type

Article

Language

eng

Format of Original

4 p.

Publication Date

8-2010

Publisher

Springer

Source Publication

Journal of Chemical Crystallography

Source ISSN

1074-1542

Abstract

Treatment of [Mo(CO)₃(NCMe)₃] with bis(diphenylphosphino)methane (dppm) and triphenylphosphine (PPh₃) at 50 °C afforded mer-[Mo(CO)₃(PPh₃)(κ²-dppm)] (1) in 55% yield which has been characterized by single crystal X-ray diffraction studies and spectroscopic measurements. Compound 1 crystallizes in the triclinic space group P−1 with a = 10.3449(6), b = 11.1570(6), c = 17.8961(10) Å, β = 80.8400(10)°, Z = 2 and V = 1959.8(2) ų.

Comments

Accepted version. Journal of Chemical Crystallography, Vol. 40, No. 8 (August 2010): 712-715. DOI. © 2010 Springer. Used with permission.

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Recommended Citation

Ghosh, Shishir; Kabir, Shariff E.; Camellia, Faranza K.; Hossain, Md. Kamal; Haworth, Daniel T.; Lindeman, Sergey V.; Siddiquee, Tasneem A.; and Bennett, Dennis W., "X-ray Structure of mer-[Mo(CO)₃(PPh₃)(κ²-dppm)]" (2010). Chemistry Faculty Research and Publications. 549.
https://epublications.marquette.edu/chem_fac/549