Title

X-ray Structure of mer-[Mo(CO)3(PPh3)(κ2-dppm)]

Document Type

Article

Language

eng

Format of Original

4 p.

Publication Date

8-2010

Publisher

Springer

Source Publication

Journal of Chemical Crystallography

Source ISSN

1074-1542

Abstract

Treatment of [Mo(CO)3(NCMe)3] with bis(diphenylphosphino)methane (dppm) and triphenylphosphine (PPh3) at 50 °C afforded mer-[Mo(CO)3(PPh3)(κ2-dppm)] (1) in 55% yield which has been characterized by single crystal X-ray diffraction studies and spectroscopic measurements. Compound 1 crystallizes in the triclinic space group P−1 with a = 10.3449(6), b = 11.1570(6), c = 17.8961(10) Å, β = 80.8400(10)°, Z = 2 and V = 1959.8(2) Å3.

Comments

Journal of Chemical Crystallography, Vol. 40, No. 8 (August 2010): 712-715. DOI.