Synthesis and Reactivity of Tricarbonyl(1-ethoxy-carbonyl-2-methylpentadienyl)iron(1+) Cation

Authors

Young K. YunFollow
Heiko Bärmann
William Donaldson, Marquette UniversityFollow

Document Type

Article

Language

eng

Publication Date

4-2001

Publisher

American Chemical Society

Source Publication

Organometallics

Source ISSN

0276-7333

Abstract

The title cation was prepared in two steps from the known (ethyl 3-methyl-6-oxo-2,4-hexadienoate)Fe(CO)3. Reation of the cation with NaBH3CN, methyl cuprate, phthalimide, water, PPh3, or malonate anions gave predominantly the products from nucleophilic attack at the C5 pentadienyl carbon.

Comments

Accepted version. Organometallics, Volume 20, No. 11 (2001): 2409-2412. DOI. © 2001 American Chemical Society. Used with permission.

Recommended Citation

Yun, Young K.; Bärmann, Heiko; and Donaldson, William, "Synthesis and Reactivity of Tricarbonyl(1-ethoxy-carbonyl-2-methylpentadienyl)iron(1+) Cation" (2001). Chemistry Faculty Research and Publications. 97.
https://epublications.marquette.edu/chem_fac/97