Unravelling a Long-Lived Ligand-to-Metal Cluster Charge Transfer State in Ce–TCPP Metal Organic Frameworks

Authors

Sizhou Yang, Marquette UniversityFollow
Wenhui Hu, Marquette University
James Nayakuchena, Marquette University
Christian Fiankor, University of Nebraska - Lincoln
Cunming Liu, Argonne National LaboratoryFollow
Eli Diego Kinigstein, Argonne National Laboratory
Jian Zhang, University of Nebraska-LincolnFollow
Xiaoyi Zhang, Argonne National LaboratoryFollow
Jier Huang, Marquette UniversityFollow

Document Type

Article

Language

eng

Publication Date

10-2020

Publisher

Royal Society of Chemistry

Source Publication

Chemical Communications

Source ISSN

1359-7345

Abstract

Metal organic frameworks (MOFs) have emerged as promising photocatalytic materials for solar energy conversion. However, a fundamental understanding of light harvesting and charge separation (CS) dynamics in MOFs remains underexplored, yet they are key factors that determine the efficiency of photocatalysis. Herein, we report the design and CS dynamics of the Ce–TCPP MOF using ultrafast spectroscopic methods.

Comments

Accepted version. Chemical Communications, Vol. 56, No. 90 (October 2020): 13971-13974. DOI. © 2020 Royal Society of Chemistry. Used with permission.

Recommended Citation

Yang, Sizhou; Hu, Wenhui; Nayakuchena, James; Fiankor, Christian; Liu, Cunming; Kinigstein, Eli Diego; Zhang, Jian; Zhang, Xiaoyi; and Huang, Jier, "Unravelling a Long-Lived Ligand-to-Metal Cluster Charge Transfer State in Ce–TCPP Metal Organic Frameworks" (2020). Chemistry Faculty Research and Publications. 1028.
https://epublications.marquette.edu/chem_fac/1028