Title

Copper-Catalyzed Arylation of 1H-Perfluoroalkanes

Document Type

Article

Language

eng

Format of Original

4 p.

Publication Date

6-2011

Publisher

American Chemical Society

Source Publication

Journal of the American Chemical Society

Source ISSN

0002-7863

Original Item ID

DOI: 10.1021/ja2041942

Abstract

A general method has been developed for arylation of readily available 1H-perfluoroalkanes. The method employs aryl iodide and 1H-perfluoroalkane reagents, DMPU solvent, TMP2Zn base, and a copper chloride/phenanthroline catalyst. Preliminary mechanistic studies are reported.

Comments

Accepted version. Journal of the American Chemical Society, Vol. 133, No. 24 (June 2011): 9286-9289. DOI. © 2011 American Chemical Society. Used with permission.

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