Copper-Catalyzed Arylation of 1H-Perfluoroalkanes

Authors

Ilya Popov, University of Houston - Main
Sergey V. Lindeman, Marquette UniversityFollow
Olafs Daugulis, University of Houston - Main

Document Type

Article

Language

eng

Format of Original

4 p.

Publication Date

6-2011

Publisher

American Chemical Society

Source Publication

Journal of the American Chemical Society

Source ISSN

0002-7863

Original Item ID

DOI: 10.1021/ja2041942

Abstract

A general method has been developed for arylation of readily available 1H-perfluoroalkanes. The method employs aryl iodide and 1H-perfluoroalkane reagents, DMPU solvent, TMP₂Zn base, and a copper chloride/phenanthroline catalyst. Preliminary mechanistic studies are reported.

Comments

Accepted version. Journal of the American Chemical Society, Vol. 133, No. 24 (June 2011): 9286-9289. DOI. © 2011 American Chemical Society. Used with permission.

Recommended Citation

Popov, Ilya; Lindeman, Sergey V.; and Daugulis, Olafs, "Copper-Catalyzed Arylation of 1H-Perfluoroalkanes" (2011). Chemistry Faculty Research and Publications. 389.
https://epublications.marquette.edu/chem_fac/389