American Chemical Society
Three di-N-pyrazolylorganyls with different conformational flexibilities in the three-atom organyl spacers have been prepared, and the self-assembly properties with AgBF4 have been studied both in solution and in the solid state. All ligands give low-coordinate silver(I) centers that are capable of participating in multiple noncovalent interactions, but only the rigid 1,8-dipyrazolylnaphthalene ligand promotes very short Ag−Ag contacts.
Liddle, Brendan J.; Hall, Daniel; Lindeman, Sergey V.; Smith, Mark D.; and Gardinier, James R., "Manipulating Self-Assembly in Silver(I) Complexes of 1,3-Di-N-pyrazolylorganyls" (2009). Chemistry Faculty Research and Publications. 603.
Accepted version. Inorganic Chemistry, Vol. 48, No. 17 (September 7, 2009): 8404-8414. DOI. © 2009 American Chemical Society. Used with permission.