Title

Manipulating Self-Assembly in Silver(I) Complexes of 1,3-Di-N-pyrazolylorganyls

Document Type

Article

Language

eng

Publication Date

9-7-2009

Publisher

American Chemical Society

Source Publication

Inorganic Chemistry

Source ISSN

0020-1669

Abstract

Three di-N-pyrazolylorganyls with different conformational flexibilities in the three-atom organyl spacers have been prepared, and the self-assembly properties with AgBF4 have been studied both in solution and in the solid state. All ligands give low-coordinate silver(I) centers that are capable of participating in multiple noncovalent interactions, but only the rigid 1,8-dipyrazolylnaphthalene ligand promotes very short Ag−Ag contacts.

Comments

Inorganic Chemistry, Vol. 48, No. 17 (September 7, 2009): 8404-8414. DOI.

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