Formation of H-bonded ionic associates in reactions of 5-nitrosalicylaldehyde with secondary amines

Authors

L. Yu Ukhin, Rostov State University
G. I. Orlova, Rostov State University
Sergey Lindeman, Marquette UniversityFollow
V. N. Khrustalev, Russian Academy of SciencesFollow
Yu T. Struchkov, Russian Academy of SciencesFollow

Document Type

Article

Language

eng

Publication Date

5-1995

Publisher

Springer

Source Publication

Russian Chemical Bulletin

Source ISSN

1066-5285

Abstract

5-Nitrosalicylaldehyde reacts with highly basic secondary aliphatic amines to form molecular complexes of 1 ∶ 1 composition. The complexes with piperidine, diethylamine, dipentylamine, and dibenzylamine (1–4, respectively) have been obtained in the crystalline state and characterized. The X-ray diffraction structural analysis of complex1 demonstrated that it exists in a crystal as an H-bonded dimeric ionic associate [C₅H₁₂N⁺· C₇H₄NO ₄ ⁻ ]₂ formed as a result of the transfer of the phenyl proton of the aldehyde to the piperidine N atom. According to the results of IR spectroscopy, the other complexes obtained have similar structures.

Comments

Russian Chemical Bulletin, Vol. 44, No. 5 (May 1995): 913-916. DOI.

Sergey Lindeman was affiliated with A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation at the time of publication.

Recommended Citation

Ukhin, L. Yu; Orlova, G. I.; Lindeman, Sergey; Khrustalev, V. N.; and Struchkov, Yu T., "Formation of H-bonded ionic associates in reactions of 5-nitrosalicylaldehyde with secondary amines" (1995). Chemistry Faculty Research and Publications. 642.
https://epublications.marquette.edu/chem_fac/642