Simultaneous Ejection of Six Electrons at a Constant Potential by Hexakis(4-ferrocenylphenyl)benzene
American Chemical Society
A simple synthesis of a dendritic hexaferrocenyl electron donor (5) is described in which six ferrocene moieties are connected at the vertices of the propeller of the hexaphenylbenzene core. The molecular structure of 5 is confirmed by X-ray crystallography. An electrochemical analysis along with redox titrations (which are tantamount to coulometry) confirmed that it ejects six electrons at a single potential.
Chebny, Vincent J.; Dhar, Dwairath; Lindeman, Sergey V.; and Rathore, Rajendra, "Simultaneous Ejection of Six Electrons at a Constant Potential by Hexakis(4-ferrocenylphenyl)benzene" (2006). Chemistry Faculty Research and Publications. 644.
Accepted version. Organic Letters, Vol. 8, No. 22 (2006): 5041-5044. DOI. © 2006 American Chemical Society. Used with permission.