A Polyaromatic Receptor with an Ethereal Fence that Directs K+ for Effective Cation−π Interaction
American Chemical Society
Journal of the American Chemical Society
We have designed and synthesized a HAB-based receptor with six ethereal oxygens on one face of the central benzene ring by a trimerization of a diarylacetylene in which the ethereal oxygens are tied together with a tetramethylene bridge. This unique amphiphilic receptor allows an efficient binding of a single potassium cation by a synergistic interaction with the polar ethereal fence and with the central benzene ring via cation−π interaction. Furthermore, the ready accessibility of this unique receptor with a bipolar binding pocket will allow the exploration of its usage for developing efficient sensing devices for various metal cations.
Shukla, Ruchi; Lindeman, Sergey V.; and Rathore, Rajendra, "A Polyaromatic Receptor with an Ethereal Fence that Directs K+ for Effective Cation−π Interaction" (2006). Chemistry Faculty Research and Publications. 648.
Accepted version. Journal of the American Chemical Society, Vol. 128, No. 16 (2006): 5328-5329. DOI. © 2006 American Chemical Society. Used with permission.