Cyclosiloxane Sandwich Complexes of a Lanthanide Metal: Na₆{[(C₆H₅SiO₂)₈]₂Nd₄(μ₄-O)}

Authors

Olga I. Shchegolikhina, Russian Academy of SciencesFollow
Yu. A. Pozdniakova, Russian Academy of SciencesFollow
Sergey V. Lindeman, Marquette UniversityFollow
Alexandr A. Zhdanov, Russian Academy of SciencesFollow
R. Psaro, University of Milan
R. Ugo, University of Milan
G. Gavioli, University of Modena
R. Battistuzzi, University of Modena
M. Borsari, University of Modena
T. Rüffer, University of Modena
C. Zucchi, University of Modena
G. Pályi, University of Modena

Document Type

Article

Language

eng

Publication Date

5-17-1996

Publisher

Elsevier

Source Publication

Journal of Organometallic Chemistry

Source ISSN

0022-328X

Abstract

The oligocyclosiloxane cluster (‘sandwich’) complex of Nd³⁺, Na₆{[(C₆H₅SiO₂)₈]₂Nd₄(μ₄-O)} has been prepared and characterized by analyses, infrared spectra, single crystal X-ray diffraction, magnetic susceptibility, conductivity and cyclic voltammetry. The μ₄-O²⁻ anion is in a square planar coordination environment. Electrochemical studies identify the cluster core as a moiety with a delocalized electron system.

Comments

Journal of Organometallic Chemistry, Vol. 514, Nos. 1-2 (May 17, 1996): 29-35. DOI.

Sergey V. Lindeman was affiliated with the Russian Academy of Sciences at the time of publication.

Recommended Citation

Shchegolikhina, Olga I.; Pozdniakova, Yu. A.; Lindeman, Sergey V.; Zhdanov, Alexandr A.; Psaro, R.; Ugo, R.; Gavioli, G.; Battistuzzi, R.; Borsari, M.; Rüffer, T.; Zucchi, C.; and Pályi, G., "Cyclosiloxane Sandwich Complexes of a Lanthanide Metal: Na₆{[(C₆H₅SiO₂)₈]₂Nd₄(μ₄-O)}" (1996). Chemistry Faculty Research and Publications. 675.
https://epublications.marquette.edu/chem_fac/675