Substituent Effects on the Nature of Hydrogen Bonding in Organic Hydroperoxides and the Structure of Triphenylmethyl Hydroperoxide
Document Type
Article
Language
eng
Publication Date
1-1990
Publisher
Springer
Source Publication
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
Source ISSN
0568-5230
Abstract
It has been found that in the crystalline state in triphenylmethyl hydroperoxide the hydroperoxy group is involved in intermolecular hydrogen-bond formation of the type O-h...π, with one C...C π-bond in a benzene ring. Conformational analysis and comparison with the results of x-ray structural analysis leads us to conclude that there are very narrow limits on the possible conformations of the COOH group in tert-butyl, cumyl, 1,1-diphenylethyl, and triphenylmethyl hydroperoxides, independent of their aggregation state or the nature of the substituent attached to the COOH group.
Recommended Citation
Antonovskii, V. L.; Kosnikov, A. Yu.; Turovskii, N. A.; Timofeeva, T. V.; Lindeman, Sergey; Struchkov, Yuri T.; and Ganyushkin, A. V., "Substituent Effects on the Nature of Hydrogen Bonding in Organic Hydroperoxides and the Structure of Triphenylmethyl Hydroperoxide" (1990). Chemistry Faculty Research and Publications. 726.
https://epublications.marquette.edu/chem_fac/726
Comments
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science, Vol. 39, No. 1 (January 1990): 57-62. DOI.
Sergey Lindeman was affiliated with A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR at the time of publication.