Structure of 2,2-bis(trifluoromethyl)-7,7-bis(trifluoromethyl)-hydroxymethyl-1,3,6-trioxaspiro [4.4]non-8-ene

Authors

A. Yu. Kosnikov, Nesmeyanov Institute of Organoelement CompoundsFollow
Sergey Lindeman, Marquette UniversityFollow
Yuri T. Struchkov, A. N. Nesmeyanov Institute of Organoelemental Compounds, Academy of Sciences of the USSRFollow
V. G. Glukhovtsev, A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR
Yu. V. Il'in, A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR

Document Type

Article

Language

eng

Publication Date

1-1990

Publisher

Springer

Source Publication

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science

Source ISSN

0568-5230

Abstract

The chemical structure of the unusual condensation product of hexafluoroacetone with 2-hydroxymethylfuran, namely 2,2-bis(trifluoromethyl)-7,7-bis(trifluoromethyl) hydroxymethyl-1,3,6-trioxaspira[4.4]non-8-ene, has been unequivocally established by x-ray structural analysis. The spiroannelated dihydrofuran and dioxalane heterocycles exist in flattened envelope and envelope conformations, respectively. An intramolecular unsymmetrical, bifurcated H-bond is also present.

Comments

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science, Vol. 39, No. 1 (January 1990): 54-56. DOI.

Sergey Lindeman was affiliated with A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR at the time of publication.

Recommended Citation

Kosnikov, A. Yu.; Lindeman, Sergey; Struchkov, Yuri T.; Glukhovtsev, V. G.; and Il'in, Yu. V., "Structure of 2,2-bis(trifluoromethyl)-7,7-bis(trifluoromethyl)-hydroxymethyl-1,3,6-trioxaspiro [4.4]non-8-ene" (1990). Chemistry Faculty Research and Publications. 727.
https://epublications.marquette.edu/chem_fac/727