Crystal and Molecular Structure of 2-Acetyl-5-Methyl-3- Phenylfuran

Authors

T.-S. Balaban, Center of Organic Chemistry
A. T. Balaban, Polytechnic Institute
D. E. Daia, Polytechnic InstituteFollow
K. M. Turdybekov, Institute of Elemento-Organic Compounds of the USSR Academy of Sciences
Sergey V. Lindeman, Marquette UniversityFollow
Yu T. Struchkov, Russian Academy of SciencesFollow

Document Type

Article

Language

eng

Publication Date

6-1992

Publisher

Springer

Source Publication

Structural Chemistry

Source ISSN

1040-0400

Abstract

The molecular structure of the title compound indicates that it possesses a transoid structure of the O=C-C-O group, and a dihedral angle of about 40° between the furan and phenyl rings. The same conformation is predominant also in CDCl₃ solution as indicated by europium chelate induced proton shifts. The corresponding 2,4-dinitrophenyhydrazone has, however, the cisoid isomer stabilized by an intramolecular hydrogen bond.

Comments

Structural Chemistry, Vol. 3, No. 3 (June 1992): 191-194. DOI.

Sergey V. Lindeman was affiliated with the Russian Academy of Sciences at the time of publication.

Recommended Citation

Balaban, T.-S.; Balaban, A. T.; Daia, D. E.; Turdybekov, K. M.; Lindeman, Sergey V.; and Struchkov, Yu T., "Crystal and Molecular Structure of 2-Acetyl-5-Methyl-3- Phenylfuran" (1992). Chemistry Faculty Research and Publications. 810.
https://epublications.marquette.edu/chem_fac/810