Title

Synthesis and Reactivity of (tricarbonyl)-(η5-2-methylpentadienyl)iron(+1) Cation

Document Type

Article

Language

eng

Publication Date

9-25-1990

Publisher

Elsevier

Source Publication

Journal of Organometallic Chemistry

Source ISSN

0022-328X

Abstract

The (tricarbonyl)(η5-2-methylpentadienyl)iron(+1) cation was prepared by the protonation of (tricarbonyl)(4-methyl-2,4-pentadienol)iron. Reaction of the cation with H2O, allyl-TMS, NaBH3CN, PPh3, malonate and 3-furyl cuprate gave (η4-1,3-diene)Fe(CO)3 complexes. The regioselectivity for the nucleophilic attack appears to be sterically controlled.

Comments

Journal of Organometallic Chemistry, Vol. 395, No. 2 (September 25, 1990): 187-193. DOI.

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