Title

5-1-substituted-pentadienyl) (tricarbonyl)iron(+1) Cations: Reactivity with Malonate Nucleophiles

Document Type

Article

Language

eng

Publication Date

1988

Publisher

Elsevier

Source Publication

Tetrahedron Letters

Source ISSN

0040-4039

Abstract

The title compounds react with malonate anions by attack at both the substituted and unsubstituted terminii, to afford the trans-cis substituted diene products.

The reaction of 1-substituted pentadienyl iron cations (R = Me, Et, n-Pro, Ph, methoxycarbonyl) with dimethylmalonate affords the products from attack at the pentadienyl terminii.

Comments

Tetrahedron Letters, Vol. 29, No. 12 (1988): 1343-1346. DOI.

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