Reactivity of (3-chloro-2-methylenecycloalkyl)palladium Chloride Dimers: Nucleophilic Attack by One or Two Equivalents of Malonate Anion

Authors

William Donaldson, Marquette UniversityFollow
Valerie J. Grief, Marquette University

Document Type

Article

Language

eng

Publication Date

1986

Publisher

Elsevier

Source Publication

Tetrahedron Letters

Source ISSN

0040-4039

Abstract

The title compounds undergo reaction with one and two equivalents of malonate anion in the presence of phosphine ligands to afford mono- and di-substituted products. A mechanism for the formation of both products is presented.

The reactivity of the title compounds 2 with malonate depends on the amount of nucleophile present.

Comments

Tetrahedron Letters, Vol. 27, No. 21 (1986): 2345-2348. DOI.

Recommended Citation

Donaldson, William and Grief, Valerie J., "Reactivity of (3-chloro-2-methylenecycloalkyl)palladium Chloride Dimers: Nucleophilic Attack by One or Two Equivalents of Malonate Anion" (1986). Chemistry Faculty Research and Publications. 852.
https://epublications.marquette.edu/chem_fac/852