A 13C NMR Study of Some Metal Acetylacetone Complexes
Journal of Inorganic and Nuclear Chemistry
13C NMR spectra of nine metal acetylacetonates in (H3C)2SO-d6 and ten metal acetylacetonates in CDCl3 are reported. The complexes are of the type M(acac)n where n is 1,2,3 or 4. The downfield shift of the methyl, methine and carbonyl carbon resonances from tetramethylsilane (TMS) are interpreted in terms of the complexed metal and a solvent effect. 13C-195Pt spin coupling is also observed for the Pt(acac)2 complex.
Wilkie, Charles A. and Haworth, Daniel T., "A 13C NMR Study of Some Metal Acetylacetone Complexes" (1978). Chemistry Faculty Research and Publications. 938.
Journal of Inorganic and Nuclear Chemistry, Vol. 40, No. 2 (1978): 195-197. DOI.