A ¹³C NMR Study of Some Metal Acetylacetone Complexes

Authors

Charles A. Wilkie, Marquette UniversityFollow
Daniel T. Haworth, Marquette UniversityFollow

Document Type

Article

Language

eng

Publication Date

1978

Publisher

Elsevier

Source Publication

Journal of Inorganic and Nuclear Chemistry

Source ISSN

0022-1902

Abstract

¹³C NMR spectra of nine metal acetylacetonates in (H₃C)₂SO-d₆ and ten metal acetylacetonates in CDCl₃ are reported. The complexes are of the type M(acac)_n where n is 1,2,3 or 4. The downfield shift of the methyl, methine and carbonyl carbon resonances from tetramethylsilane (TMS) are interpreted in terms of the complexed metal and a solvent effect. ¹³C-¹⁹⁵Pt spin coupling is also observed for the Pt(acac)₂ complex.

Comments

Journal of Inorganic and Nuclear Chemistry, Vol. 40, No. 2 (1978): 195-197. DOI.

Recommended Citation

Wilkie, Charles A. and Haworth, Daniel T., "A ¹³C NMR Study of Some Metal Acetylacetone Complexes" (1978). Chemistry Faculty Research and Publications. 938.
https://epublications.marquette.edu/chem_fac/938