Title

Ultraviolet-induced Surface Grafting of Octafluoropentyl Methacrylate on Polyether Ether Ketone for Inducing Antibiofilm Properties

Document Type

Article

Language

eng

Publication Date

7-2017

Publisher

SAGE Publications

Source Publication

Journal of Biomaterials Applications

Source ISSN

0885-3282

Abstract

Since octafluoropentyl methacrylate is an antifouling polymer, surface modification of polyether ether ketone with octafluoropentyl methacrylate is a practical approach to obtaining anti-biofilm biocompatible devices. In the current study, the surface treatment of polyether ether ketone by the use of ultraviolet irradiation, so as to graft (octafluoropentyl methacrylate) polymer chains, was initially implemented and then investigated. The Fourier-transform infrared and nuclear magnetic resonance spectra corroborated the appearance of new signals associated with the fluoroacrylate group. Thermogravimetric curves indicated enhanced asymmetry in the polymer structure due to the introduction of the said new groups. Measuring the peak area in differential scanning calorimetry experiments also showed additional bond formation. Static water contact angle measurements indicated a change in wettability to the more hydrophobic surface. The polyether ether ketone–octafluoropentyl methacrylate surface greatly reduced the protein adsorption. This efficient method can modulate and tune the surface properties of polyether ether ketone according to specific applications.

Comments

Journal of Biomaterials Applications, Vol. 32, No. 1 (July 2017): 3-11. DOI.

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