Preparation of a Semiquinonate-Bridged Diiron(II) Complex and Elucidation of its Geometric and Electronic Structures

Authors

Amanda E. Baum, Marquette UniversityFollow
Sergey V. Lindeman, Marquette UniversityFollow
Adam T. Fiedler, Marquette UniversityFollow

Document Type

Article

Publication Date

7-2013

Source Publication

Chemical Communications

Source ISSN

1359-7345

Abstract

The synthesis and crystal structure of a diiron(II) complex containing a bridging semiquinonate radical are presented. The unique electronic structure of this S = 7/2 complex is examined with spectroscopic (absorption, EPR, resonance Raman) and computational methods.

Comments

Accepted version. Chemical Communications, Vol. 49, No. 58 (July 2013): 6531-6533. DOI. © 2013 Royal Society of Chemistry. Used with permission.

Recommended Citation

Baum, Amanda E.; Lindeman, Sergey V.; and Fiedler, Adam T., "Preparation of a Semiquinonate-Bridged Diiron(II) Complex and Elucidation of its Geometric and Electronic Structures" (2013). Chemistry Faculty Research and Publications. 404.
https://epublications.marquette.edu/chem_fac/404