Bromobis(dimethyldithiocarbamato)(4-methoxyphenyl)tellurium(IV) Dichloromethane Hemisolvate, p-MeOC₆H₄Te(Me₂NCS₂)₂Br.0.5CH₂Cl₂

Authors

Steinar Husebye, University of Bergen
Steffen Kudis, University of Heidelberg
Sergey V. Lindeman, Marquette UniversityFollow

Document Type

Article

Language

eng

Publication Date

1996

Publisher

International Union of Crystallography

Source Publication

Acta Crystallographica Section C

Source ISSN

0108-2701

Abstract

The structure of the title Te^IV complex, C₁₃H₁₉BrN₂OS₄Te.045(CH₂Cl₂), is pentagonal bipyramidal with four S atoms [Te-S 2.623 (1)-2.717 (1) Å] and the Br atom [Te-Br 2.890 (1) Å] in equatorial positions. The p-methoxyphenyl group is axial [Te-C 2.145 (3) Å] and the second axial position seems to be occupied by a dithiocarbamate group of a neighbouring molecule acting as a -ligand [TeC 3.751 (3) Å, C-TeC 170.2 (1)°], so that molecules are joined into centrosymmetric associations by this secondary coordination.

Comments

Published version. Acta Crystallographica Section C, Vol. 52 (1996): 429-432. DOI. © 1996 International Union of Crystallography. Used with permission.

Recommended Citation

Husebye, Steinar; Kudis, Steffen; and Lindeman, Sergey V., "Bromobis(dimethyldithiocarbamato)(4-methoxyphenyl)tellurium(IV) Dichloromethane Hemisolvate, p-MeOC₆H₄Te(Me₂NCS₂)₂Br.0.5CH₂Cl₂" (1996). Chemistry Faculty Research and Publications. 588.
https://epublications.marquette.edu/chem_fac/588