Document Type
Article
Language
eng
Publication Date
8-2009
Publisher
Springer
Source Publication
Journal of Chemical Crystallography
Source ISSN
1074-1542
Abstract
Treatment of Mn2(CO)10 with 2-thiazoline-2-thiol in the presence of Me3NO at room temperature afforded the dimanganese complexes [Mn2(CO)7(μ-NS2C3H4)2] (1) and [Mn2(CO)6(μ-NS2C3H4)2] (2) in 51 and 34% yields, respectively. Compound 1 was quantitatively converted into 2 when reacted with one equiv of Me3NO. Reaction of 1 with triphenylphosphine at room temperature furnished the mononuclear complex [Mn(CO)3(PPh3)(κ 2-NS2C3H4)] (3) in 66% yield. All three new complexes have been characterized by elemental analyzes and spectroscopic data together with single crystal X-ray diffraction studies for 1 and 3. Compound 1 crystallizes in the orthorhombic space group Pbca with a = 12.4147(2), b = 16.2416(3), c = 19.0841(4) Å, β = 90°, Z = 8 and V = 3848.01(12) Å3 and 3 crystallizes in the monoclinic space group P 21/n with a = 10.41730(10), b = 14.7710(2), c = 14.9209(2) Å, β = 91.1760(10)°, Z = 4 and V = 2295.45(5) Å3.
Recommended Citation
Ghosh, Shishir; Ahmed, Faruque; Al-Mamun, Rafique; Haworth, Daniel T.; Lindeman, Sergey V.; Siddiquee, Tasneem; Bennett, Dennis W.; and Kabir, Shariff E., "Investigations of 2-Thiazoline-2-thiol as a Ligand: Synthesis and X-ray Structures of [Mn2(CO)7(μ-NS2C3H4)2] and [Mn(CO)3(PPh3)(κ2-NS2C3H4)]" (2009). Chemistry Faculty Research and Publications. 607.
https://epublications.marquette.edu/chem_fac/607
Comments
Accepted version. Journal of Chemical Crystallography, Vol. 39, No. 8 (August 2009): 595-602. DOI. © 2009 Springer. Used with permission.
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