Document Type
Article
Language
eng
Publication Date
2007
Publisher
American Chemical Society
Source Publication
The Journal of Organic Chemistry
Source ISSN
0022-3263
Abstract
We have demonstrated that reactions of diphenylmethyllithium with a variety of substituted benzophenones produces corresponding tertiary alcohols that are easily dehydrated, without any need for purification, to produce various unsymmetrical and symmetrical tetraarylethylenes in excellent yields. The simplicity of the method allows for the preparation of a variety of ethylenic derivatives in multigram (10−50 g) quantities with great ease. The methodology was successfully employed for the preparation of various triphenylethylene (TPE)-based triads (i.e., TPE−spacer−TPE) containing polyphenylene and fluoranyl-based spacers. The ready availability of various substituted tetraarylethylenes allowed us to shed light on the effect of substituents on the oxidation potentials (Eox) of various tetraarylethylenes. Moreover, the electronic coupling among the triphenylethylene moieties in various TPE−spacer−TPE triads was briefly probed by electrochemical and optical methods.
Recommended Citation
Banerjee, Moloy; Emond, Susanna J.; Lindeman, Sergey V.; and Rathore, Rajendra, "Practical Synthesis of Unsymmetrical Tetraarylethylenes and Their Application for the Preparation of [Triphenylethylene−Spacer−Triphenylethylene] Triads" (2007). Chemistry Faculty Research and Publications. 625.
https://epublications.marquette.edu/chem_fac/625
Comments
Accepted version. The Journal of Organic Chemistry, Vol. 72, No. 21 (2007): 8054-8061. DOI. © 2007 American Chemical Society. Used with permission.