Synthesis and Characterization of platinum – selenium Derivatives: X-ray Structure of trans-Pt(Pet₃)₂(SePh)₂

Authors

Martin D. Rudd, University of Wisconsin - Fox ValleyFollow
Sergey V. Lindeman, Marquette UniversityFollow

Document Type

Article

Language

eng

Publication Date

5-2007

Publisher

Springer

Source Publication

Journal of Chemical Crystallography

Source ISSN

1074-1542

Abstract

The crystal structure of trans-[((bis)triethylphosphine)(bis(phenylselenato))platinum (II)] has been determined by single crystal X-ray diffraction. Crystallization occurs in the triclinic space group P-1 (No. 2) with a = 8.9964(2) Å, b = 11.5103(2) Å, c = 14.9335(3) Å; α = 85.8750(10)°, β = 72.5350(10)°, γ = 68.4450(10)°. Details of the structure and spectroscopic results are presented and discussed and comparisons are made with related square planar platinum (II) structures.

Comments

Accepted version. Journal of Chemical Crystallography, Vol. 37, No. 5 (May 2007): 375-379. DOI. © 2007 Springer Science+Business Media, LLC. Used with permission.

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Recommended Citation

Rudd, Martin D. and Lindeman, Sergey V., "Synthesis and Characterization of platinum – selenium Derivatives: X-ray Structure of trans-Pt(Pet₃)₂(SePh)₂" (2007). Chemistry Faculty Research and Publications. 631.
https://epublications.marquette.edu/chem_fac/631