Structures of Polymetallaorganosiloxanolates—a Novel Class of Organosilicon Metal Complexes

Authors

Yu T. Struchkov, Russian Academy of SciencesFollow
Sergey V. Lindeman, Marquette UniversityFollow

Document Type

Article

Language

eng

Publication Date

2-22-1995

Publisher

Elsevier

Source Publication

Journal of Organometallic Chemistry

Source ISSN

0022-328X

Abstract

Single crystal X-ray diffraction studies have revealed the nature and structure of eight types (I–VIII) of polymetallaorganosiloxanolates, representatives of a novel class of the organosilicon metal complexes. Most of the complexes (types I–VII) have sandwich structures with a layer of metal cations between two macrocyclic siloxanolate ligands. In type VIII a single such ligand envelops four inner Cu²⁺ ions to form a globular species.

Comments

Journal of Organometallic Chemistry, Vol. 488, No. 1-2 (February 22, 1995): 9-14. DOI.

Sergey Lindeman was affiliated with A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Russia at the time of publication.

Recommended Citation

Struchkov, Yu T. and Lindeman, Sergey V., "Structures of Polymetallaorganosiloxanolates—a Novel Class of Organosilicon Metal Complexes" (1995). Chemistry Faculty Research and Publications. 652.
https://epublications.marquette.edu/chem_fac/652