Study of Structural Aspects of Thermochemical Conversions of Compounds Modeling Oligophenylenes Containing Acenaphthylenyl and Acenaphthenyl Groups

Authors

A. I. Kovalev, Russian Academy of Sciences
T. N. Balykova, Russian Academy of Sciences
Sergey Lindeman, Marquette UniversityFollow
M. M. Teplyakov, Russian Academy of Sciences
I. A. Khotina, Russian Academy of Sciences
A. L. Rusanov, Russian Academy of SciencesFollow
Yu T. Struchkov, Russian Academy of SciencesFollow

Document Type

Article

Language

eng

Publication Date

5-1994

Publisher

Springer

Source Publication

Russian Chemical Bulletin

Source ISSN

1066-5285

Abstract

With the aim of elucidating the mechanism of the thermochemical conversion of oligophenylenes containing acenaphthylenyl groups, the thermolysis of model compounds: l,3,5-tris(5-acenaphthylenyl)benzene (1), 1,3,5-tris(5-acenaphthenyl)benzene (2), acenaphthylene, and acenaphthene, was studied by differential thermal analysis (DTA), dynamic thermogravimetric analysis (TGA), and mass spectrometry. Compounds1and2 were studied by X-ray structural analysis. A scheme for the formation of secondary structures was suggested. Optimum temperature conditions were found for preparing thermostable, heat-resistant, and stable to thermooxidation polymers based on compounds containing the acenaphthylenyl groups.

Comments

Russian Chemical Bulletin, Vol. 43, No. 5 (May 1994): 790-798. DOI.

Sergey Lindeman was affiliated with Russian Academy of Sciences at the time of publication.

Recommended Citation

Kovalev, A. I.; Balykova, T. N.; Lindeman, Sergey; Teplyakov, M. M.; Khotina, I. A.; Rusanov, A. L.; and Struchkov, Yu T., "Study of Structural Aspects of Thermochemical Conversions of Compounds Modeling Oligophenylenes Containing Acenaphthylenyl and Acenaphthenyl Groups" (1994). Chemistry Faculty Research and Publications. 685.
https://epublications.marquette.edu/chem_fac/685