Document Type
Article
Language
eng
Publication Date
2000
Publisher
American Chemical Society
Source Publication
Organic Letters
Source ISSN
1523-7060
Abstract
Extensive (electron) delocalization in the novel heteromolecular π-complex of the hindered naphthalene cation radical (OMN+•) with naphthalene (NAP) accompanies the pronounced charge-transfer absorption band at ∼1100 nm in the near-IR. X-ray crystallography establishes the viability of the unusual “club sandwich” structure despite the repulsive electrostatic forces inherent to the dicationic unit.
Recommended Citation
Maguères, P. Le; Lindeman, Sergey V.; and Kochi, Jay K., "Novel (Heteromolecular) π-Complexes of Aromatic Cation Radicals. Isolation and Structural Characterization" (2000). Chemistry Faculty Research and Publications. 689.
https://epublications.marquette.edu/chem_fac/689
Comments
Accepted version. Organic Letters, Vol. 2, No. 23 (2000): 3567-3570. DOI. © 2000 American Chemical Society. Used with permission.
Sergey V. Lindeman was affiliated with the University of Houston at the time of publication.