Synthesis and Structure of 6-chloro-2,3-trimethylene-4-phenylquinoline

Authors

Igor I. Ponomarev, Russian Academy of SciencesFollow
O. V. Shishkin, Russian Academy of SciencesFollow
Sergey V. Lindeman, Marquette UniversityFollow
Yu. V. Volkova, Russian Academy of Sciences

Document Type

Article

Language

eng

Publication Date

7-1996

Publisher

Springer

Source Publication

Russian Chemical Bulletin

Source ISSN

1066-5285

Abstract

An X-ray structural investigation of 6-chloro- 2,3-trimethylene-4- phe nylquinoli ne obtained by the reaction of 2-amino-5-chlorobenzophenone with cyclopentanone was carried out. At 20 °C, a = 23.750,b = 9,242, c = 14.018 A, β = 112,68° space group (21c,Z = 8, 2647 reflections,R = 0.047 He five-membered ring has an envelope conformation Conjugation between the quinohne fragment and the phenyl substituent is significantly distorted dm to the rotation of the latter by -62.9°

Comments

Russian Chemical Bulletin, Vol. 45, No. 7 (July 1996): 1711-1713. DOI.

Sergey V. Lindeman was affiliated with the Russian Academy of Sciences at the time of publication.

Recommended Citation

Ponomarev, Igor I.; Shishkin, O. V.; Lindeman, Sergey V.; and Volkova, Yu. V., "Synthesis and Structure of 6-chloro-2,3-trimethylene-4-phenylquinoline" (1996). Chemistry Faculty Research and Publications. 700.
https://epublications.marquette.edu/chem_fac/700