Synthesis, Structures, and Properties of Spiro[6-Azaperimidine-2,4′-Cyclohexa-2′,5′-Dien]-1′-One Derivatives

Authors

V. N. Komissarov, Rostov State University
E. N. Gruzdeva, Rostov State University
L. P. Olekhnovich, Rostov State University
G. S. Borodkin, Rostov State University
V. N. Khrustalev, Russian Academy of SciencesFollow
Sergey V. Lindeman, Marquette UniversityFollow
Yu T. Struchkov, Russian Academy of SciencesFollow
V. A. Kogan, Rostov State University
V. I. Minkin, Rostov State University

Document Type

Article

Language

eng

Publication Date

11-1997

Publisher

Springer

Source Publication

Russian Chemical Bulletin

Source ISSN

1066-5285

Abstract

The reaction of 5-amino-4-chloroquinolines with 4-amino-2,6-di-tert-butylphenol yielded derivatives of spiro[6-azaperimidine-2,4′-cyclohexa-2′,5′-dien]-1′-one, which exhibit photo-and thermochromic properties in solutions. The structure of 2′,6′-di-tert-butyl-5,7,9-trimethylspiro[6-aza,-2,3-dihydroperimidine-2,4′-cyclohexa-2′,5′-dien]-1′-one was established by X-ray diffraction study. The ring-chain isomerization of 2′,6′-di-tert-butyl-5,7-dimethyl-and 2′,6′-di-tert-butyl-5,7,8-trimethylspiro[6-aza-2,3-dihydroperimidine-2,4′-cyclohexa-2′,5′-dien]-1′-ones was studied by dynamic NMR spectroscopy.

Comments

Russian Chemical Bulletin, Vol. 46, No. 11 (November 1997): 1924-1930. DOI.

Sergey V. Lindeman was affiliated with the Russian Academy of Sciences at the time of publication.

Recommended Citation

Komissarov, V. N.; Gruzdeva, E. N.; Olekhnovich, L. P.; Borodkin, G. S.; Khrustalev, V. N.; Lindeman, Sergey V.; Struchkov, Yu T.; Kogan, V. A.; and Minkin, V. I., "Synthesis, Structures, and Properties of Spiro[6-Azaperimidine-2,4′-Cyclohexa-2′,5′-Dien]-1′-One Derivatives" (1997). Chemistry Faculty Research and Publications. 706.
https://epublications.marquette.edu/chem_fac/706