Structure of 5-nitro-2-tosylaminobenzaldehyde di(morpholin-4-yl)aminal Complex with Carbon Tetrachloride

Authors

V. N. Khrustalev, Russian Academy of SciencesFollow
Sergey V. Lindeman, Marquette UniversityFollow
L. Yu Ukhin, Rostov State University
G. I. Orlova, Rostov State University
T. N. Gribanova, Rostov State University
O. V. Shishkin, Russian Academy of SciencesFollow

Document Type

Article

Language

eng

Publication Date

5-1998

Publisher

De Gruyter

Source Publication

Zeitschrift für Kristallographie - Crystalline Materials

Source ISSN

2196-7105

Abstract

The 5-nitro-2-tosylaminobenzaldehyde di(morpholin-4-yl)aminal forms a stable complex with carbon tetrachloride in the crystal phase. X-ray structural study of this complex indicates an essentially shortened intermolecular contact of 2.89 Å between the oxygen atom of the nitro group and one of the chlorine atom of the CCI₄ molecule. Quantum-chemical calculations by semiempirical AMI method showed that the formation of such complex did not cause considerable decrease of system energy or change of charge distribution in molecules. It was supposed that this associate has van der Waals character.

Comments

Published version. Zeitschrift für Kristallographie - Crystalline Materials, Vol. 213, No. 5 (May 1998): 296-298. DOI. © 1998 De Gruyter. Used with permission.

Sergey V. Lindeman was affiliated with the Russian Academy of Sciences at the time of publication.

Recommended Citation

Khrustalev, V. N.; Lindeman, Sergey V.; Ukhin, L. Yu; Orlova, G. I.; Gribanova, T. N.; and Shishkin, O. V., "Structure of 5-nitro-2-tosylaminobenzaldehyde di(morpholin-4-yl)aminal Complex with Carbon Tetrachloride" (1998). Chemistry Faculty Research and Publications. 708.
https://epublications.marquette.edu/chem_fac/708