Reactivity of acyclic (pentadienyl)iron(1+) cations with weak carbon nucleophiles

Authors

M. Azad Hossain, Marquette University
Myung-Jong JinFollow
William Donaldson, Marquette UniversityFollow

Document Type

Article

Publication Date

7-2001

Publisher

Elsevier

Source Publication

Journal of Organometallic Chemistry

Source ISSN

0022-328x

Abstract

The reaction of acyclic tricarbonyl(pentadienyl)iron(1+) cations with allyl trimethylsilane or with excess furan leads to (E,E-diene)iron complexes. Attack of these weak nucleophiles on the transoid form of the pentadienyl cation is presumably faster than attack on the more stable cisoid form.

Comments

Accepted version. Journal of Organometallic Chemistry, Vol. 630, Issue 1 (2001), pp. 5-10. DOI: 10.1016/S0022-328X(01)00869-5. © 2001 Elsevier. Used with permission.

Recommended Citation

Hossain, M. Azad; Jin, Myung-Jong; and Donaldson, William, "Reactivity of acyclic (pentadienyl)iron(1+) cations with weak carbon nucleophiles" (2001). Chemistry Faculty Research and Publications. 71.
https://epublications.marquette.edu/chem_fac/71