Journal of Organometallic Chemistry
The reaction of acyclic tricarbonyl(pentadienyl)iron(1+) cations with allyl trimethylsilane or with excess furan leads to (E,E-diene)iron complexes. Attack of these weak nucleophiles on the transoid form of the pentadienyl cation is presumably faster than attack on the more stable cisoid form.
Hossain, M. Azad; Jin, Myung-Jong; and Donaldson, William, "Reactivity of acyclic (pentadienyl)iron(1+) cations with weak carbon nucleophiles" (2001). Chemistry Faculty Research and Publications. 71.
ADA Accessible Version
Accepted version. Journal of Organometallic Chemistry, Vol. 630, Issue 1 (2001), pp. 5-10. DOI: 10.1016/S0022-328X(01)00869-5. © 2001 Elsevier. Used with permission.