Macrobicyclic D-Metal Tris-Dioximates Obtained by Cross-Linking With P-Block Elements Part IV. Crystalline and Molecular Structure Of An Iron(II) Complex With Macrobicyclic Fluoroborate-Containing Tris-Diphenylglyoximate Ligand And Its Mössbauer

Authors

Sergey Lindeman, Marquette UniversityFollow
Yuri T. Struchkov, Nesmeyanov Institute of Organoelement CompoundsFollow
Yan Z. Voloshin, Institute of General and Inorganic ChemistryFollow

Document Type

Article

Language

eng

Publication Date

6-1-1991

Publisher

Elsevier

Source Publication

Inorganica Chimica Acta

Source ISSN

0020-1693

Abstract

Hexagonal FeBd₃(BF)₂·5CHCl₃ single crystals (space group P6₃, a=14.975(2), c=16.301(3) Å, V=3166(1) ų, Z=2) have been obtained by recrystallizing a preliminarily synthesized clathrochelate diphenyl- glyoximate complex. The iron atom is encapsulated by the macrobicyclic ligand and surrounded by a distorted trigonal prismatic coordination consisting of six nitrogen atoms. The distortion angle value found experimentally (c. 29.3°) is close to that estimated earlier from Mössbauer parameters (27–30°). The FeN bond length (1.91(2) Å) is characteristic of clathrochelate boron-containing iron(II) dioximates and is determined by the superposition of the contributions of metal eletron configuration and ligand geometry.

Comments

Inorganica Chimica Acta, Vol. 184, No. 1 (June 1, 1991): 107-110. DOI.

Sergey Lindeman was affiliated with Nesmeyanov Institute of Organoelement Compounds of the Academy of Sciences of the USSR at the time of publication.

Recommended Citation

Lindeman, Sergey; Struchkov, Yuri T.; and Voloshin, Yan Z., "Macrobicyclic D-Metal Tris-Dioximates Obtained by Cross-Linking With P-Block Elements Part IV. Crystalline and Molecular Structure Of An Iron(II) Complex With Macrobicyclic Fluoroborate-Containing Tris-Diphenylglyoximate Ligand And Its Mössbauer" (1991). Chemistry Faculty Research and Publications. 719.
https://epublications.marquette.edu/chem_fac/719