Nontrivial Intramolecular Interaction in Ozonation of Dimethyl Ester of endo,cis-bicyclo[2,2,1]hept-5-en-2,3-dicarbonic acid in diethyl ether
Document Type
Article
Language
eng
Publication Date
1985
Publisher
Elsevier
Source Publication
Tetrahedron Letters
Source ISSN
0040-4039
Abstract
The formation of the product of intramolecular interaction of a zwitterion and a methoxycarbonyl group was observed in the process of ozonating dimethyl ester of endo,cis-bicyclo [2,2,1]hept-5-en-2,3-dicarbonic acid in diethyl ether. The structure of racemic endo,cis-4-methoxy-5-methoxycarbonyl-6-formyl-1,4-epoxy-2,3-dioxacyclopenta[2,3-δ] cyclohexane was established by an X-ray structure analysis.
Recommended Citation
Odinokov, Viktor N.; Kukovinets, Olga S.; Khalilov, Leonard M.; Tolstikov, Genrikh A.; Kosnikov, A. Yu.; Lindeman, Sergey; and Struchkov, Yu T., "Nontrivial Intramolecular Interaction in Ozonation of Dimethyl Ester of endo,cis-bicyclo[2,2,1]hept-5-en-2,3-dicarbonic acid in diethyl ether" (1985). Chemistry Faculty Research and Publications. 743.
https://epublications.marquette.edu/chem_fac/743
Comments
Tetrahedron Letters, Vol. 26, No. 47 (1985): 5843-5844. DOI.
Sergey Lindeman was affiliated with Academy of Sciences of the USSR at the time of publication.