Molecular Structure of 4,4′-Dimethoxydibenzoyl Peroxide

Authors

A. Yu. Kosnikov, Academy of Sciences of the USSRFollow
V. L. Antonovskii, Academy of Sciences of the USSRFollow
Sergey Lindeman, Marquette UniversityFollow
Yu T. Struchkov, Academy of Sciences of the USSRFollow
I. P. Zyat'kov, Academy of Sciences of the USSR
G. A. Pitsevich, Academy of Sciences of the USSR
V. I. Gogolinskii, Academy of Sciences of the USSR

Document Type

Article

Language

eng

Publication Date

4-1985

Publisher

Springer

Source Publication

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science

Source ISSN

1066-5285

Abstract

Conclusions

An x-ray diffraction structural analysis gave the geometrical parameters of 4,4′-dimethoxydibenzoyl peroxide and dibenzoyl peroxide. The Raman spectra were also taken for these two peroxides. The introduction of electron-donor substituents into dibenzoyl peroxide causes a decrease in the COOC dihedral angle, νC=O frequency and strength, of the O-O bond with retention of the O-O and C=O bond lengths within experimental error.

Comments

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science,Vol. 34, No. 4 (April 1985): 855-857. DOI.

Sergey Lindeman was affiliated with Academy of Sciences of the USSR at the time of publication.

Recommended Citation

Kosnikov, A. Yu.; Antonovskii, V. L.; Lindeman, Sergey; Struchkov, Yu T.; Zyat'kov, I. P.; Pitsevich, G. A.; and Gogolinskii, V. I., "Molecular Structure of 4,4′-Dimethoxydibenzoyl Peroxide" (1985). Chemistry Faculty Research and Publications. 744.
https://epublications.marquette.edu/chem_fac/744