A Carbon-13 Nuclear Magnetic Resonance Study of Some Pentanedionato Complexes of Silicon and Germanium

Authors

Daniel T. Haworth, Marquette UniversityFollow
Gong-Yu Lin, Marquette UniversityFollow
Charles Wilkie, Marquette UniversityFollow

Document Type

Article

Language

eng

Publication Date

1980

Publisher

Elsevier

Source Publication

Inorganica Chimica Acta

Source ISSN

0020-1693

Abstract

The ¹³C NMR spectra of Si(acac)₂Cl₂ Si(acac)₂(acetato)₂, Si(acac)₃Cl, Ge(acac)₂ Cl₂, Ge(acac)₂Br₂ and Ge(acac)₃I are reported. The data is consistent with the disproportionation of Si(acac)₂Cl₂ into Si(acac)₃Cl and SiCl₄, whereas Si(acac)₂(acetato)₂ Ge(acac)₂Cl₂ and Ge(acac)₂Br₂ each exist in solution as a mixture of cis and trans isomers. The carbon atoms of the cis isomers of these compounds are not exchanging at room temperature.

Comments

Inorganica Chimca Acta, Vol. 40 (1980): 119-121. DOI.

Recommended Citation

Haworth, Daniel T.; Lin, Gong-Yu; and Wilkie, Charles, "A Carbon-13 Nuclear Magnetic Resonance Study of Some Pentanedionato Complexes of Silicon and Germanium" (1980). Chemistry Faculty Research and Publications. 789.
https://epublications.marquette.edu/chem_fac/789