Nucleophilic Addition to Coordinated Polyenes: A Novel Method for the Liberation of the Trimethylenemethane Ligand Involving CC Bond Formation

Authors

William Donaldson, Marquette UniversityFollow
M. Azad Hossain, Marquette University

Document Type

Article

Language

eng

Publication Date

7-14-1992

Publisher

Elsevier

Source Publication

Tetrahedron Letters

Source ISSN

0040-4039

Abstract

Reaction of (trimethylenemethane)Fe(CO)₃ with carbon nucleophiles, followed by protonation yields the corresponding methallylated nucleophile in good yield. Products which incorporate carbonyl ligands are also observed.

Reaction of (trimethylenemethane) Fe (CO)₃ complexes with carbanion nucleophiles, followed by protonolysis, gives the corresponding methallylated product in good yield.

Comments

Tetrahedron Letters, Vol. 33, No. 29 (July 14, 1992): 4107-4110. DOI.

Recommended Citation

Donaldson, William and Hossain, M. Azad, "Nucleophilic Addition to Coordinated Polyenes: A Novel Method for the Liberation of the Trimethylenemethane Ligand Involving CC Bond Formation" (1992). Chemistry Faculty Research and Publications. 845.
https://epublications.marquette.edu/chem_fac/845