Title

Nucleophilic Addition to Coordinated Polyenes: A Novel Method for the Liberation of the Trimethylenemethane Ligand Involving CC Bond Formation

Document Type

Article

Language

eng

Publication Date

7-14-1992

Publisher

Elsevier

Source Publication

Tetrahedron Letters

Source ISSN

0040-4039

Abstract

Reaction of (trimethylenemethane)Fe(CO)3 with carbon nucleophiles, followed by protonation yields the corresponding methallylated nucleophile in good yield. Products which incorporate carbonyl ligands are also observed.

Reaction of (trimethylenemethane) Fe (CO)3 complexes with carbanion nucleophiles, followed by protonolysis, gives the corresponding methallylated product in good yield.

Comments

Tetrahedron Letters, Vol. 33, No. 29 (July 14, 1992): 4107-4110. DOI.

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