Dicarbon­yl{[(E,E)-(2,3,4,5-η)-6-meth­­oxy-6-oxo-2,4-hexa­dien­yl]tri­phenyl­phospho­nium}(tri­phenyl­phosphane-κP)iron(1+) hexa­fluorido­phosphate

Authors

Yuzhi Ma, Marquette University
Sergey V. Lindeman, Marquette UniversityFollow
William A. Donaldson, Marquette UniversityFollow

Document Type

Article

Language

eng

Publication Date

2018

Publisher

International Union of Crystallography

Source Publication

Studia Graeco-Arabica

Source ISSN

2414-3146

Abstract

In the title compound, [Fe(C₂₅H₂₄O₂P)(C₁₈H₁₅P)(CO)₂]PF₆, the Fe atom adopts a square-based pyramidal coordination geometry with the carbonyl groups and the two C=C bonds of the diene defining the basal sites and the phosphane ligand the apical position. The diene ligand has an E,E geometry, with the phospho­nium fragment pointed away from the Fe atom. The crystal structure displays C—H⋯F and C—H⋯O hydrogen bonding. The PF₆⁻ anion is rotationally disordered over four orientations.

Comments

Published version. IUCrData, Vol. 3, Part 6 (June 2018): x180902. DOI. © 2018 International Union of Crystallography. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Recommended Citation

Ma, Yuzhi; Lindeman, Sergey V.; and Donaldson, William A., "Dicarbon­yl{[(E,E)-(2,3,4,5-η)-6-meth­­oxy-6-oxo-2,4-hexa­dien­yl]tri­phenyl­phospho­nium}(tri­phenyl­phosphane-κP)iron(1+) hexa­fluorido­phosphate" (2018). Chemistry Faculty Research and Publications. 955.
https://epublications.marquette.edu/chem_fac/955