Title

Dicarbonyl{[(E,E)-(2,3,4,5-g)-6-methoxy-6-oxo-2,4- hexadienyl]triphenylphosphonium}(triphenylphosphane- jP)iron(1+) hexafluoridophosphate

Document Type

Article

Language

eng

Publication Date

2018

Publisher

International Union of Crystallography

Source Publication

Studia Graeco-Arabica

Source ISSN

2414-3146

Abstract

In the title compound, [Fe(C25H24O2P)(C18H15P)(CO)2]PF6, the Fe atom adopts a square-based pyramidal coordination geometry with the carbonyl groups and the two C=C bonds of the diene defining the basal sites and the phosphane ligand the apical position. The diene ligand has an E,E geometry, with the phospho­nium fragment pointed away from the Fe atom. The crystal structure displays C—H⋯F and C—H⋯O hydrogen bonding. The PF6 anion is rotationally disordered over four orientations.

Comments

IUCrData, Vol. 3, Part 6 (June 2018): x180902. DOI.

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