Thermodynamic Properties of Se-Te(l) Described by an Extension of the Two Domain Model

Authors

Robert F. Brebrick, Marquette UniversityFollow

Document Type

Article

Publication Date

6-2016

Publisher

Springer

Source Publication

Journal of Phase Equilibria and Diffusion

Source ISSN

1547-7037

Abstract

The two domain model of Se-Te liquid is developed further than heretofore. Explicit equations are obtained for the excess Gibbs energy of mixing, the chemical potentials, the enthalpy of mixing, the relative constant pressure heat capacity, and the partial and total pressures. A generally satisfactory fit is obtained for the experimental activity of Te and enthalpy of mixing at 733 K, the relative heat capacity as a function of temperature, and for the total pressure for 99, 60, and 27 at.% Se between about 780 and 1130 K. This is done while leaving unchanged the site fraction of H or (Te-like) and L (or Se-like) domains previously used to fit a number of physical properties.

Comments

Accepted version. Journal of Phase Equilibria and Diffusion, Vol. 37, No. 3 (June 2016): 327-335. DOI. © 2016 Springer. Used with permission.

Recommended Citation

Brebrick, Robert F., "Thermodynamic Properties of Se-Te(l) Described by an Extension of the Two Domain Model" (2016). Mechanical Engineering Faculty Research and Publications. 260.
https://epublications.marquette.edu/mechengin_fac/260